Intramolecular rearrangement reactions of tris-chelate complexes. II. Kinetics and probable mechanism of the isomerization and racemization of the "fast" complexes tris(1-phenyl-5-methylhexane-2,4-dionato)aluminum(III) and -gallium(III)

Richard H. Holm; J. R. Hutchison; Joseph Grover Gordon

doi:10.1021/ic50099a031

Intramolecular rearrangement reactions of tris-chelate complexes. II. Kinetics and probable mechanism of the isomerization and racemization of the "fast" complexes tris(1-phenyl-5-methylhexane-2,4-dionato)aluminum(III) and -gallium(III)

Inorganic Chemistry ◽

10.1021/ic50099a031 ◽

1971 ◽

Vol 10 (5) ◽

pp. 1004-1017 ◽

Cited By ~ 40

Author(s):

Richard H. Holm ◽

J. R. Hutchison ◽

Joseph Grover Gordon

Keyword(s):

Probable Mechanism ◽

Intramolecular Rearrangement ◽

Chelate Complexes ◽

Rearrangement Reactions

Intramolecular rearrangement reactions of tris-chelate complexes. I. General theory and the kinetics and probable mechanism of the isomerization and racemization of tris(5-methylhexane-2,4-dionato)cobalt(III)

Journal of the American Chemical Society ◽

10.1021/ja00721a007 ◽

1970 ◽

Vol 92 (18) ◽

pp. 5319-5332 ◽

Cited By ~ 68

Author(s):

Joseph G. Gordon ◽

Richard H. Holm

Keyword(s):

General Theory ◽

Probable Mechanism ◽

Intramolecular Rearrangement ◽

Chelate Complexes ◽

Rearrangement Reactions

Intramolecular rearrangement reactions of tris-chelate complexes. IV. Rearrangements of tris(.alpha.-isopropenyl- and .alpha.-isopropyltropolonate)metal(III,IV) complexes

Journal of the American Chemical Society ◽

10.1021/ja00785a020 ◽

1973 ◽

Vol 95 (4) ◽

pp. 1116-1124 ◽

Cited By ~ 40

Author(s):

S. S. Eaton ◽

G. R. Eaton ◽

R. H. Holm ◽

E. L. Muetterties

Keyword(s):

Intramolecular Rearrangement ◽

Chelate Complexes ◽

Rearrangement Reactions

Intramolecular rearrangement reactions of tris-chelate complexes. III. Analysis of the rearrangements of tris(.alpha.-isopropenyl- and .alpha.-isopropyltropolonato)aluminum(III) and -cobalt(III). Examples of stereochemically nonrigid aluminum(III) and cobalt(III) complexes

Journal of the American Chemical Society ◽

10.1021/ja00773a026 ◽

1972 ◽

Vol 94 (18) ◽

pp. 6411-6426 ◽

Cited By ~ 55

Author(s):

S. S. Eaton ◽

J. R. Hutchison ◽

R. H. Holm ◽

E. L. Muetterties

Keyword(s):

Intramolecular Rearrangement ◽

Chelate Complexes ◽

Rearrangement Reactions

Domino and Intramolecular Rearrangement Reactions as Advanced Synthetic Methods in Glycosciences. Edited by Z. J. Witczak and R. Bielski .

Angewandte Chemie International Edition ◽

10.1002/anie.201606642 ◽

2016 ◽

Vol 55 (38) ◽

pp. 11337-11338

Author(s):

Steven J. Sucheck

Keyword(s):

Synthetic Methods ◽

Intramolecular Rearrangement ◽

Rearrangement Reactions

Umlagerungsreaktionen von lithiierten Silylhydroxylaminen mit Fluorsilanen / Rearrangement Reactions of Lithiated Silylhydroxylamines with Fluorosilanes

Zeitschrift für Naturforschung B ◽

10.1515/znb-1981-1102 ◽

1981 ◽

Vol 36 (11) ◽

pp. 1356-1360 ◽

Cited By ~ 2

Author(s):

Dieter Bentmann ◽

Uwe Klingebiel

Keyword(s):

Intramolecular Rearrangement ◽

Analogous Reaction ◽

Rearrangement Reactions

Abstract Halogenosilanes, with the exception of CH3SiF3 and SiF4, react with lithiated bis-(trimethylsilyl)hydroxylamine in ether to yield substituted hydroxylamines, and LiF. In the analogous reaction with trifluoromethylsilane and tetrafluorosilane the products undergo an intramolecular rearrangement to form silylaminosiloxanes.

Domino and Intramolecular Rearrangement Reactions as Advanced Synthetic Methods in Glycoscience

10.1002/9781119044222 ◽

2016 ◽

Cited By ~ 1

Keyword(s):

Synthetic Methods ◽

Intramolecular Rearrangement ◽

Rearrangement Reactions

The Hammond Postulate and the Principle of Maximum Hardness in Some Intramolecular Rearrangement Reactions

The Journal of Physical Chemistry A ◽

10.1021/jp990576e ◽

1999 ◽

Vol 103 (44) ◽

pp. 8847-8852 ◽

Cited By ~ 37

Author(s):

Miquel Solà ◽

Alejandro Toro-Labbé

Keyword(s):

Intramolecular Rearrangement ◽

Maximum Hardness ◽

Rearrangement Reactions ◽

Principle Of Maximum

Dynamics of intramolecular metal-centered rearrangement reactions of tris-chelate complexes

Theoretical Inorganic Chemistry - Topics in Current Chemistry ◽

10.1007/bfb0050629 ◽

2006 ◽

pp. 91-137 ◽

Cited By ~ 22

Author(s):

Louis H. Pignolet

Keyword(s):

Chelate Complexes ◽

Rearrangement Reactions

Intramolecular rearrangement reactions of tris(N-methyl-N-benzyldithiocarbamato)-iron(IV) tetrafluoroborate by proton magnetic resonance

Inorganic Chemistry ◽

10.1021/ic50117a054 ◽

1972 ◽

Vol 11 (11) ◽

pp. 2843-2845 ◽

Cited By ~ 17

Author(s):

D. J. Duffy ◽

L. H. Pignolet

Keyword(s):

Magnetic Resonance ◽

Proton Magnetic Resonance ◽

Intramolecular Rearrangement ◽

Rearrangement Reactions

Ab Initio SCF and DFT Studies on Solvent Effects on Intramolecular Rearrangement Reactions

The Journal of Physical Chemistry A ◽

10.1021/jp0021345 ◽

2001 ◽

Vol 105 (17) ◽

pp. 4272-4283 ◽

Cited By ~ 42

Author(s):

Pratim K. Chattaraj ◽

Patricia Pérez ◽

Jenny Zevallos ◽

Alejandro Toro-Labbé

Keyword(s):

Ab Initio ◽

Solvent Effects ◽

Intramolecular Rearrangement ◽

Dft Studies ◽

Rearrangement Reactions