Intramolecular rearrangement reactions of tris-chelate complexes. I. General theory and the kinetics and probable mechanism of the isomerization and racemization of tris(5-methylhexane-2,4-dionato)cobalt(III)

1970 ◽  
Vol 92 (18) ◽  
pp. 5319-5332 ◽  
Author(s):  
Joseph G. Gordon ◽  
Richard H. Holm
Keyword(s):  
General Theory ◽  
Probable Mechanism ◽  
Intramolecular Rearrangement ◽  
Chelate Complexes ◽  
Rearrangement Reactions

Umlagerungsreaktionen von lithiierten Silylhydroxylaminen mit Fluorsilanen / Rearrangement Reactions of Lithiated Silylhydroxylamines with Fluorosilanes

1981 ◽  
Vol 36 (11) ◽  
pp. 1356-1360 ◽  
Author(s):  
Dieter Bentmann ◽  
Uwe Klingebiel
Keyword(s):  
Intramolecular Rearrangement ◽  
Analogous Reaction ◽  
Rearrangement Reactions

Abstract Halogenosilanes, with the exception of CH3SiF3 and SiF4, react with lithiated bis-(trimethylsilyl)hydroxylamine in ether to yield substituted hydroxylamines, and LiF. In the analogous reaction with trifluoromethylsilane and tetrafluorosilane the products undergo an intramolecular rearrangement to form silylaminosiloxanes.

The Hammond Postulate and the Principle of Maximum Hardness in Some Intramolecular Rearrangement Reactions

1999 ◽  
Vol 103 (44) ◽  
pp. 8847-8852 ◽  
Author(s):  
Miquel Solà ◽  
Alejandro Toro-Labbé
Keyword(s):  
Intramolecular Rearrangement ◽  
Maximum Hardness ◽  
Rearrangement Reactions ◽  
Principle Of Maximum

Ab Initio SCF and DFT Studies on Solvent Effects on Intramolecular Rearrangement Reactions

2001 ◽  
Vol 105 (17) ◽  
pp. 4272-4283 ◽  
Author(s):  
Pratim K. Chattaraj ◽  
Patricia Pérez ◽  
Jenny Zevallos ◽  
Alejandro Toro-Labbé
Keyword(s):  
Ab Initio ◽  
Solvent Effects ◽  
Intramolecular Rearrangement ◽  
Dft Studies ◽  
Rearrangement Reactions
Sign in / Sign up

Export Citation Format

Share Document