Resonance Raman spectra of iron tetraphenylporphyrin complexes: characterization of structure and bonding sensitive bands

1981 ◽  
Vol 20 (6) ◽  
pp. 1718-1722 ◽  
Author(s):  
Genevieve. Chottard ◽  
Pierrette. Battioni ◽  
Jean Paul. Battioni ◽  
Marc. Lange ◽  
Daniel. Mansuy
Keyword(s):  
Raman Spectra ◽  
Resonance Raman ◽  
Structure And Bonding ◽  
Resonance Raman Spectra

ChemInform Abstract: RESONANCE RAMAN SPECTRA OF IRON TETRAPHENYLPORPHYRIN COMPLEXES: CHARACTERIZATION OF STRUCTURE AND BONDING SENSITIVE BANDS

1981 ◽  
Vol 12 (36) ◽  
Author(s):  
G. CHOTTARD ◽  
P. BATTIONI ◽  
J.-P. BATTIONI ◽  
M. LANGE ◽  
D. MANSUY
Keyword(s):  
Raman Spectra ◽  
Resonance Raman ◽  
Structure And Bonding ◽  
Resonance Raman Spectra

Resonance Raman spectra of 15N enriched metallooctaethylorphyrins. Characterization of the oxidation state marker bands of hemoproteins

1977 ◽  
Vol 48 (1) ◽  
pp. 55-58 ◽  
Author(s):  
T. Kitagawa ◽  
M. Abe ◽  
Y. Kyogoku ◽  
H. Ogoshi ◽  
H. Sugimoto ◽  
...  
Keyword(s):  
Raman Spectra ◽  
Oxidation State ◽  
Resonance Raman ◽  
State Marker ◽  
Resonance Raman Spectra

Darstellung und spektroskopische Charakterisierung von Nitridophthalocyaninatomangan(V) / Preparation and Spectroscopical Characterization of Nitridophthalocyaninatomanganese(V)

1990 ◽  
Vol 45 (4) ◽  
pp. 483-489 ◽  
Author(s):  
Horst Grunewald ◽  
Heiner Homborg
Keyword(s):  
Electron Transfer ◽  
Raman Spectra ◽  
Electronic Transition ◽  
Resonance Raman ◽  
Cation Radical ◽  
Strong Resonance ◽  
Resonance Enhancement ◽  
Resonance Raman Spectra

Nitridophthalocyaninatomanganese(V), MnNPc(2–), has been prepared by oxidation of [Mn(OH)2,Pc(2–)]- with chlorine in the presence of excess ammonia in dichloromethane as a chemically very stable, diamagnetic microcrystalline blue powder. The band at 1053 cm-1 in the infrared and resonance Raman spectra is assigned to v(Mn=N). The strong resonance enhancement of v(Mn=N) coincides with an electronic transition at 461 nm assigned to (N → Mn) electron transfer. The UV-VIS spectrum in 1-chloronaphthalene is compared with that of the MnNPc(2–)–H2SO4 adduct and the phthalocyanine-π-cation radical [MnNPc(1–)]+.

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