Mechanisms of the Water−Gas-Shift Reaction by Iron Pentacarbonyl in the Gas Phase

Xavier Rozanska; Rodolphe Vuilleumier

doi:10.1021/ic8001866

Mechanisms of the Water−Gas-Shift Reaction by Iron Pentacarbonyl in the Gas Phase

Inorganic Chemistry ◽

10.1021/ic8001866 ◽

2008 ◽

Vol 47 (19) ◽

pp. 8635-8640 ◽

Cited By ~ 23

Author(s):

Xavier Rozanska ◽

Rodolphe Vuilleumier

Keyword(s):

Gas Phase ◽

Iron Pentacarbonyl ◽

Water Gas Shift ◽

Water Gas Shift Reaction ◽

Shift Reaction ◽

Water Gas

ChemInform Abstract: FORMATION AND REACTIVITY OF THE IRON CARBOXYLIC ACID ANION FE(CO)4COOH- IN THE GAS PHASE. IMPLICATIONS FOR THE IRON PENTACARBONYL-CATALYZED WATER-GAS SHIFT REACTION

Chemischer Informationsdienst ◽

10.1002/chin.198503307 ◽

1985 ◽

Vol 16 (3) ◽

Author(s):

K. R. LANE ◽

R. E. LEE ◽

L. SALLANS ◽

R. R. SQUIRES

Keyword(s):

Carboxylic Acid ◽

Gas Phase ◽

Iron Pentacarbonyl ◽

Water Gas Shift ◽

Water Gas Shift Reaction ◽

Acid Anion ◽

Carboxylic Acid Anion ◽

Shift Reaction ◽

Water Gas

Formation and reactivity of the iron carboxylic acid anion Fe(CO)4COOH- in the gas phase. Implications for the iron pentacarbonyl-catalyzed water-gas shift reaction

Journal of the American Chemical Society ◽

10.1021/ja00332a001 ◽

1984 ◽

Vol 106 (20) ◽

pp. 5767-5772 ◽

Cited By ~ 33

Author(s):

Kelley R. Lane ◽

Robert E. Lee ◽

Larry Sallans ◽

Robert R. Squires

Keyword(s):

Carboxylic Acid ◽

Gas Phase ◽

Iron Pentacarbonyl ◽

Water Gas Shift ◽

Water Gas Shift Reaction ◽

Acid Anion ◽

Carboxylic Acid Anion ◽

Shift Reaction ◽

Water Gas

Theoretical Study of the Gas-Phase Fe(CO)5Catalyzed Water Gas Shift Reaction: A New Mechanism Proposed

Inorganic Chemistry ◽

10.1021/ic049159t ◽

2004 ◽

Vol 43 (26) ◽

pp. 8236-8238 ◽

Cited By ~ 21

Author(s):

Susan E. Barrows

Keyword(s):

Gas Phase ◽

Theoretical Study ◽

Water Gas Shift ◽

Water Gas Shift Reaction ◽

Shift Reaction ◽

Water Gas

Direct Pathway for Water–Gas Shift Reaction in Gas Phase

Chemistry Letters ◽

10.1246/cl.130940 ◽

2014 ◽

Vol 43 (2) ◽

pp. 193-195 ◽

Cited By ~ 4

Author(s):

Yu Harabuchi ◽

Satoshi Maeda ◽

Tetsuya Taketsugu ◽

Koichi Ohno

Keyword(s):

Gas Phase ◽

Water Gas Shift ◽

Water Gas Shift Reaction ◽

Direct Pathway ◽

Shift Reaction ◽

Water Gas

Theoretical Study of the Proton Transfer between Water and [FeH(CO)4]-in Aqueous Solution and Relevance to the Water-Gas Shift Reaction Catalyzed by Iron Pentacarbonyl in the Condensed Phase

Organometallics ◽

10.1021/om000854s ◽

2001 ◽

Vol 20 (7) ◽

pp. 1310-1316 ◽

Cited By ~ 10

Author(s):

Claudio Amovilli ◽

Franca Maria Floris ◽

Miquel Solà ◽

Jacopo Tomasi

Keyword(s):

Aqueous Solution ◽

Proton Transfer ◽

Condensed Phase ◽

Theoretical Study ◽

Iron Pentacarbonyl ◽

Water Gas Shift ◽

Water Gas Shift Reaction ◽

Shift Reaction ◽

Water Gas

Theoretical Study of Gas-Phase Reactions of Fe(CO)5with OH-and Their Relevance for the Water Gas Shift Reaction

Organometallics ◽

10.1021/om9810504 ◽

1999 ◽

Vol 18 (15) ◽

pp. 2801-2812 ◽

Cited By ~ 43

Author(s):

Maricel Torrent ◽

Miquel Solà ◽

Gernot Frenking

Keyword(s):

Gas Phase ◽

Theoretical Study ◽

Water Gas Shift ◽

Water Gas Shift Reaction ◽

Gas Phase Reactions ◽

Shift Reaction ◽

Water Gas

Reactions of iron pentacarbonyl and dihydrogen tetracarbonylferrate related to the water-gas shift reaction

Journal of the American Chemical Society ◽

10.1021/ja00366a020 ◽

1982 ◽

Vol 104 (2) ◽

pp. 500-504 ◽

Cited By ~ 40

Author(s):

Ralph G. Pearson ◽

Heiko Mauermann

Keyword(s):

Iron Pentacarbonyl ◽

Water Gas Shift ◽

Water Gas Shift Reaction ◽

Shift Reaction ◽

Water Gas

ChemInform Abstract: REACTIONS OF IRON PENTACARBONYL AND DIHYDROGEN TETRACARBONYLFERRATE RELATED TO THE WATER-GAS SHIFT REACTION

Chemischer Informationsdienst ◽

10.1002/chin.198218289 ◽

1982 ◽

Vol 13 (18) ◽

Author(s):

R. G. PEARSON ◽

H. MAUERMANN

Keyword(s):

Iron Pentacarbonyl ◽

Water Gas Shift ◽

Water Gas Shift Reaction ◽

Shift Reaction ◽

Water Gas

ChemInform Abstract: HOMOGENEOUS CATALYSIS OF THE WATER GAS SHIFT REACTION USING IRON PENTACARBONYL

Chemischer Informationsdienst ◽

10.1002/chin.198018082 ◽

1980 ◽

Vol 11 (18) ◽

Author(s):

A. D. JUN. KING ◽

R. B. KING ◽

D. B. YANG

Keyword(s):

Homogeneous Catalysis ◽

Iron Pentacarbonyl ◽

Water Gas Shift ◽

Water Gas Shift Reaction ◽

Shift Reaction ◽

Water Gas

Effect of Water Vapour on the Equilibrium Between CaO and COS in Coal Gas

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19990157 ◽

1999 ◽

Vol 64 (1) ◽

pp. 157-167 ◽

Cited By ~ 1

Author(s):

Miloslav Hartman ◽

Karel Svoboda ◽

Otakar Trnka

Keyword(s):

Phase Composition ◽

Gas Phase ◽

Water Vapour ◽

Carbonyl Sulfide ◽

Water Gas Shift ◽

Calcium Sulfide ◽

Water Gas Shift Reaction ◽

Coal Gas ◽

Shift Reaction ◽

Water Gas

The effectiveness of calcium oxide in the removal of carbonyl sulfide from coal gas is estimated by thermochemical computations. It is assumed that the gas phase composition is determined by the equilibria of the reactions of water vapour with calcium sulfide and carbonyl sulfide and by the water-gas-shift reaction. The proposed relationships can be employed in engineering considerations and calculations.