Magnesium Substitutions in Rare-Earth Metal Germanides with the Orthorhombic Gd5Si4-type Structure. Synthesis, Crystal Chemistry, and Magnetic Properties ofRE5−xMgxGe4(RE= Gd−Tm, Lu, and Y)

2009 ◽  
Vol 48 (14) ◽  
pp. 6641-6651 ◽  
Author(s):  
Paul H. Tobash ◽  
Svilen Bobev ◽  
Joe D. Thompson ◽  
John L. Sarrao
1994 ◽  
Vol 49 (11) ◽  
pp. 1525-1530 ◽  
Author(s):  
Rainer Pöttgen

The new ternary stannides RE2Au2Sn (RE = Gd, Tb) and indides RE2Au2In (RE = Y, Gd-Tm, Lu) were synthesized by arc-melting of the elemental components and subsequent annealing at 800 °C. While Gd2Au2Sn, Tb2Au2Sn and the indides with RE = Y, Gd-Er crystallize in the ordered U3Si2 structure, Tm2Au2In and Lu2Au2In adopt the ordered Zr3Al2 structure, respectively. The crystal structure of Dy2Au2In was refined from single-crystal X- ray data: P4/mbm, Z = 2, a = 784.1(1) pm, c = 373.9(1) pm, V = 0.2299 nm3 and R = 0.028 for 342 F2 values and 12 variables. The tin (indium) atoms in these compounds occupy [RE8] square prisms and the gold atoms are surrounded by [RE6] trigonal prisms. These fragments are derived from the AlB2 and CsCl-type structures. The crystal chemistry of these com­pounds is briefly discussed.


2014 ◽  
Vol 2014 (16) ◽  
pp. 2631-2642 ◽  
Author(s):  
Inna Bigun ◽  
Mariya Dzevenko ◽  
Ladislav Havela ◽  
Yaroslav Kalychak

ChemInform ◽  
2014 ◽  
Vol 45 (30) ◽  
pp. no-no
Author(s):  
Inna Bigun ◽  
Mariya Dzevenko ◽  
Ladislav Havela ◽  
Yaroslav Kalychak

ChemInform ◽  
2010 ◽  
Vol 42 (4) ◽  
pp. no-no
Author(s):  
Volodymyr Babizhetskyy ◽  
Arndt Simon ◽  
Hansjuergen Mattausch ◽  
Kurt Hiebl ◽  
Chong Zheng

2003 ◽  
Vol 67 (14) ◽  
Author(s):  
Yuji Iyeiri ◽  
Teppei Okumura ◽  
Chishiro Michioka ◽  
Kazuya Suzuki

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