Oxidative Dehydrogenation ofn-Butane in a Two-Zone Fluidized-Bed Reactor

1999 ◽  
Vol 38 (1) ◽  
pp. 90-97 ◽  
Author(s):  
J. Soler ◽  
J. M. López Nieto ◽  
J. Herguido ◽  
M. Menéndez ◽  
J. Santamaría



2000 ◽  
Vol 61 (1-4) ◽  
pp. 101-107 ◽  
Author(s):  
M.L Pacheco ◽  
J Soler ◽  
A Dejoz ◽  
J.M López Nieto ◽  
J Herguido ◽  
...  


AIChE Journal ◽  
2016 ◽  
Vol 63 (1) ◽  
pp. 43-50 ◽  
Author(s):  
Julius Rischard ◽  
Robert Franz ◽  
Claudia Antinori ◽  
Olaf Deutschmann


2016 ◽  
Vol 511 ◽  
pp. 23-30 ◽  
Author(s):  
Julius Rischard ◽  
Claudia Antinori ◽  
Lubow Maier ◽  
Olaf Deutschmann


2010 ◽  
Vol 49 (21) ◽  
pp. 10279-10286 ◽  
Author(s):  
Vincenzo Palma ◽  
Diana Sannino ◽  
Vincenzo Vaiano ◽  
Paolo Ciambelli


AIChE Journal ◽  
2004 ◽  
Vol 50 (7) ◽  
pp. 1510-1522 ◽  
Author(s):  
O. Rubio ◽  
J. Herguido ◽  
M. Menéndez ◽  
G. Grasa ◽  
J. C. Abanades


2009 ◽  
Vol 2009 ◽  
pp. 1-7 ◽  
Author(s):  
Paolo Ciambelli ◽  
Diana Sannino ◽  
Vincenzo Palma ◽  
Vincenzo Vaiano ◽  
Roberto S. Mazzei

The performances of a gas-solid two-dimensional fluidized bed reactor in photocatalytic selective oxidation reactions, irradiated with traditional UV lamps or with a microscale illumination system based on UV emitting diodes (UVA-LEDs), have been compared. In the photocatalytic oxidative dehydrogenation of cyclohexane to benzene on catalyst the use of UVA-LEDs modules allowed to achieve a cyclohexane conversion and benzene yield higher than those obtained with traditional UV lamps. The better performances with UVA-LEDs are due to the UVA-LEDs small dimensions and small-angle emittance, which allow photons beam be directed towards the photoreactor windows, reducing the dispersion outside of photoreactor or the optical path length. As a consequence, the effectively illuminated mass of catalyst is greater. We have found that this illumination system is efficient for photo-oxidative dehydrogenation of cyclohexane to cyclohexene on sulphated and ethanol to acetaldehyde on .



2012 ◽  
Vol 2012 ◽  
pp. 1-9 ◽  
Author(s):  
J. J. Murcia ◽  
M. C. Hidalgo ◽  
J. A. Navío ◽  
V. Vaiano ◽  
P. Ciambelli ◽  
...  

Ethanol oxidative dehydrogenation over Pt/TiO2photocatalyst, in the presence and absence of blue phosphors, was performed. The catalyst was prepared by photodeposition of Pt on sulphated TiO2. This material was tested in a gas-solid photocatalytic fluidized bed reactor at high illumination efficiency. The effect of the addition of blue phosphors into the fluidized bed has been evaluated. The synthesized catalysts were extensively characterized by different techniques. Pt/TiO2with a loading of 0.5 wt% of Pt appeared to be an active photocatalyst in the selective partial oxidation of ethanol to acetaldehyde improving its activity and selectivity compared to pure TiO2. In the same way, a notable enhancement of ethanol conversion in the presence of the blue phosphors has been obtained. The blue phosphors produced an increase in the level of ethanol conversion over the Pt/TiO2catalyst, keeping at the same time the high selectivity to acetaldehyde.



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