Insertion and oxidative addition reactions of rhodium porphyrin complexes. Novel free radical chain mechanisms

1985 ◽  
Vol 107 (14) ◽  
pp. 4333-4335 ◽  
Author(s):  
Ralph S. Paonessa ◽  
Nicholas C. Thomas ◽  
Jack Halpern
Keyword(s):  
Free Radical ◽  
Oxidative Addition ◽  
Addition Reactions ◽  
Radical Chain

Relative Reactivities of 1,1,1-Trichloroethane and 1,1,1-Trichlorotrifluoroethane in Competitive Addition Reactions

1992 ◽  
Vol 57 (6) ◽  
pp. 1291-1298 ◽  
Author(s):  
František Adámek ◽  
Milan Hájek ◽  
Zbyněk Janoušek
Keyword(s):  
Free Radical ◽  
Reaction Mechanism ◽  
Relative Reactivity ◽  
Addition Reactions ◽  
Radical Initiation ◽  
Amine Complexes ◽  
Free Radical Initiation ◽  
Ru Complexes ◽  
Radical Initiators

Relative reactivity of CH3CCl3 and CF3CCl3 measured in competitive addition reactions with 1-hexene in the presence of free radical initiators or Cu, Pd and Ru complexes was found to depend on the type of catalyst. The unusual course of the reaction has been found in the additions catalyzed with copper(I)-amine complexes where CH3CCl3 in competition with CF3CCl3 was completely unreactive. The results have been explained in terms of the change of reaction mechanism and compared with classical free radical initiation.

Oxidative addition reactions of an iridium(I) complex containing phosphine-NHC

Polyhedron ◽  
2021 ◽  
Vol 198 ◽  
pp. 115083
Author(s):  
Aziza Ahmida ◽  
Fatin M. Elmagbari ◽  
Hans Egold ◽  
Gerald Henkel
Keyword(s):  
Oxidative Addition ◽  
Addition Reactions
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