ChemInform Abstract: MECHANISTIC STUDIES OF SOME OXIDATIVE-ADDITION REACTIONS: FREE-RADICAL PATHWAYS IN THE PT0-RX, PT0-PHBR, AND PTII-R′SO2X REACTIONS (R = ALKYL, R′ = ARYL, X = HALIDE) AND IN THE RELATED RHODIUM(I) OR IRIDIUM(I) SYSTEMS

1980 ◽  
Vol 11 (46) ◽  
Author(s):  
T. L. HALL ◽  
M. F. LAPPERT ◽  
P. W. LEDNOR
1992 ◽  
Vol 57 (6) ◽  
pp. 1291-1298 ◽  
Author(s):  
František Adámek ◽  
Milan Hájek ◽  
Zbyněk Janoušek

Relative reactivity of CH3CCl3 and CF3CCl3 measured in competitive addition reactions with 1-hexene in the presence of free radical initiators or Cu, Pd and Ru complexes was found to depend on the type of catalyst. The unusual course of the reaction has been found in the additions catalyzed with copper(I)-amine complexes where CH3CCl3 in competition with CF3CCl3 was completely unreactive. The results have been explained in terms of the change of reaction mechanism and compared with classical free radical initiation.


Polyhedron ◽  
2021 ◽  
Vol 198 ◽  
pp. 115083
Author(s):  
Aziza Ahmida ◽  
Fatin M. Elmagbari ◽  
Hans Egold ◽  
Gerald Henkel

2018 ◽  
Vol 37 (15) ◽  
pp. 2450-2467 ◽  
Author(s):  
Ryley Kehoe ◽  
Markshun Mahadevan ◽  
Adeela Manzoor ◽  
Gillian McMurray ◽  
Patrick Wienefeld ◽  
...  

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