Electron spin resonance studies of substituent effects. III. Electron withdrawal by Group IV and Group VI elements

1970 ◽  
Vol 92 (8) ◽  
pp. 2327-2336 ◽  
Author(s):  
E. Thomas. Strom ◽  
Jack R. Norton



1968 ◽  
Vol 21 (5) ◽  
pp. 1155 ◽  
Author(s):  
R Colton ◽  
CJ Rix

Complexes of the general formula Mo(CO)2L2X2 (L = pyridine (py), 2,2'- dipyridyl (dipy), 1,l0-phenanthroline (phen); X = Cl, Br) have been isolated. The pyrldine derivatives are yellow monomeric compounds which are paramagnetic, but the complexes with dipy and phen contain diamagnetic seven-coordinate cations and are correctly formulated as [Mo(CO)2L2X]+X-. Conductance, infrared, magnetic, and electron spin resonance studies have been carried out.





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