Diastereoselective Addition of γ-Substituted Allylic Nucleophiles to Ketones:  Highly Stereoselective Synthesis of Tertiary Homoallylic Alcohols Using an Allylic Tributylstannane/Stannous Chloride System

2002 ◽  
Vol 124 (45) ◽  
pp. 13442-13447 ◽  
Author(s):  
Makoto Yasuda ◽  
Kay Hirata ◽  
Mitsuyoshi Nishino ◽  
Akihiro Yamamoto ◽  
Akio Baba
Keyword(s):  
Stereoselective Synthesis ◽  
Stannous Chloride ◽  
Chloride System ◽  
Homoallylic Alcohols ◽  
Diastereoselective Addition

Highly stereoselective synthesis of vicinal diols by stannous chloride-mediated addition of hydroxyallylic stannanes to aldehydes

2009 ◽  
Vol 50 (26) ◽  
pp. 3209-3212 ◽  
Author(s):  
Makoto Yasuda ◽  
Tatsuya Azuma ◽  
Kensuke Tsuruwa ◽  
Srinivasarao Arulananda Babu ◽  
Akio Baba
Keyword(s):  
Stereoselective Synthesis ◽  
Stannous Chloride ◽  
Vicinal Diols

Regio- and Stereoselective Synthesis of Homoallylic Alcohols Based on the Use of (3-Chloroprop-1-en-1-yl)boronates.

ChemInform ◽  
2003 ◽  
Vol 34 (1) ◽  
pp. no-no
Author(s):  
Marco Lombardo ◽  
Stefano Morganti ◽  
Massimo Tozzi ◽  
Claudio Trombini
Keyword(s):  
Stereoselective Synthesis ◽  
Homoallylic Alcohols

Diastereoselective Synthesis of Morpholine Derivatives from Grignard Reagents and N-Sulfinyl Imines

Synlett ◽  
2021 ◽  
Author(s):  
Eric P. A. Talbot ◽  
Joseph M. Bateman ◽  
Diana Chan ◽  
Mustafa Moroglu ◽  
Benjamin Rahemtulla
Keyword(s):  
Grignard Reagent ◽  
Stereoselective Synthesis ◽  
Grignard Reagents ◽  
Diastereoselective Synthesis ◽  
Step Process ◽  
Diastereoselective Addition ◽  
Morpholine Derivatives

The stereoselective synthesis of C3-substituted morpholine derivatives has been achieved through a two-step process involving diastereoselective addition of a Grignard reagent to a sulfinyl imine, followed by cyclization.

Catalytic carboboration of dienylboronate for stereoselective synthesis of (E)-γ′,δ-bisboryl-anti-homoallylic alcohols

2019 ◽  
Vol 55 (75) ◽  
pp. 11199-11202 ◽  
Author(s):  
Shang Gao ◽  
Ming Chen
Keyword(s):  
Stereoselective Synthesis ◽  
Homoallylic Alcohols

A Cu-catalyzed stereoselective carboboration of dienylboronate for the synthesis of (E)-γ′,δ-bisboryl-anti-homoallylic alcohols was developed.

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