In Situ Hydrogenation of Terminal Halogen in Poly(methyl methacrylate) by Ruthenium-Catalyzed Living Radical Polymerization:  Direct Transformation of “Polymerization Catalyst” into “Hydrogenation Catalyst”

2006 ◽  
Vol 128 (34) ◽  
pp. 11014-11015 ◽  
Author(s):  
Takaya Terashima ◽  
Makoto Ouchi ◽  
Tsuyoshi Ando ◽  
Mitsuo Sawamoto
Keyword(s):  
Methyl Methacrylate ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Hydrogenation Catalyst ◽  
Direct Transformation ◽  
Poly Methyl Methacrylate ◽  
Polymerization Catalyst

Aqueous emulsion polymerizations of methacrylates and styrene via reversible complexation mediated polymerization (RCMP)

2021 ◽  
Author(s):  
Weijia Mao ◽  
Jit Sarkar ◽  
Bo Peng ◽  
Atsushi Goto
Keyword(s):  
Methyl Methacrylate ◽  
Emulsion Polymerization ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Aqueous Emulsion ◽  
Poly Methyl Methacrylate ◽  
Emulsion Polymerizations

Aqueous emulsion polymerization via reversible complexation mediated living radical polymerization yielded low-dispersity poly(methyl methacrylate)s and polystyrenes.

Synthesis of fluorinated gradient copolymers via in situ transesterification with fluoroalcohols in tandem living radical polymerization

2017 ◽  
Vol 8 (15) ◽  
pp. 2299-2308 ◽  
Author(s):  
Yusuke Ogura ◽  
Takaya Terashima ◽  
Mitsuo Sawamoto
Keyword(s):  
Methyl Methacrylate ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Titanium Alkoxide ◽  
Tandem Catalysis ◽  
In Situ Transesterification ◽  
Gradient Copolymers

Fluorinated gradient copolymers were synthesized by the tandem catalysis of ruthenium-catalyzed living radical polymerization and titanium alkoxide-mediated transesterification of methyl methacrylate (MMA) with fluoroalcohols.

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