The Shortest Metal−Metal Bond Yet:  Molecular and Electronic Structure of a Dinuclear Chromium Diazadiene Complex

2007 ◽  
Vol 129 (46) ◽  
pp. 14162-14163 ◽  
Author(s):  
Kevin A. Kreisel ◽  
Glenn P. A. Yap ◽  
Olga Dmitrenko ◽  
Clark R. Landis ◽  
Klaus H. Theopold
Keyword(s):  
Electronic Structure ◽  
Metal Bond ◽  
Metal Metal ◽  
Molecular And Electronic Structure

Electronic structure of a (cyclopentadienyl)tri-.mu.-oxoditechnetium polymer with a very short metal-metal bond

1991 ◽  
Vol 30 (5) ◽  
pp. 1086-1093 ◽  
Author(s):  
A. W. Edith. Chan ◽  
Roald. Hoffmann ◽  
Santiago. Alvarez
Keyword(s):  
Electronic Structure ◽  
Metal Bond ◽  
Metal Metal

The He(I) and He(II) Photoelectron Spectra of Tm2Zn (Tm = (C5H5)Fe(CO)2, (C5H5)M(CO)3; M = Cr, Mo, W)

1984 ◽  
Vol 39 (9) ◽  
pp. 1206-1210
Author(s):  
Jaap N. Louwen ◽  
Derk J. Stufkens ◽  
Ad Oskam
Keyword(s):  
Electronic Structure ◽  
Transition Metals ◽  
Ionization Energy ◽  
Photoelectron Spectra ◽  
Metal Bond ◽  
Metal Metal

UV photoelectron spectra of the title compounds are reported. Assignments are made with the help of He(I)/He(II) intensity differences, shift effects upon substitution and comparison with related molecules. Previously drawn conclusions about the electronic structure of similar com­plexes also hold for the compounds. It is indicated that the ionization energy for the symmetric metal-metal bond strongly depends on the overlap between transition and post-transition metals.

Metal–metal bond length variations and the electronic structure of dichromium(II) and dimolybdenum(II) complexes

1983 ◽  
pp. 1085-1089 ◽  
Author(s):  
Paul M. Atha ◽  
John C. Campbell ◽  
C. David Garner ◽  
Ian H. Hillier ◽  
Alastair A. MacDowell
Keyword(s):  
Electronic Structure ◽  
Bond Length ◽  
Metal Bond ◽  
Metal Metal

Rhodium and ruthenium tetracarboxylate nitrosyl complexes: Electronic structure and metal-metal bond

2007 ◽  
Vol 33 (8) ◽  
pp. 588-593 ◽  
Author(s):  
O. V. Sizova ◽  
L. V. Skripnikov ◽  
A. Yu. Sokolov ◽  
N. V. Ivanova
Keyword(s):  
Electronic Structure ◽  
Metal Bond ◽  
Nitrosyl Complexes ◽  
Metal Metal

Low-Valent Vanadium Complexes of a Pyrrolide-Based Ligand. Electronic Structure of a Dimeric V(I) Complex with a Short and Weak Metal−Metal Bond

2008 ◽  
Vol 47 (8) ◽  
pp. 3265-3273 ◽  
Author(s):  
Sougandi Ilango ◽  
Balamurugan Vidjayacoumar ◽  
Sandro Gambarotta ◽  
Serge I. Gorelsky
Keyword(s):  
Electronic Structure ◽  
Vanadium Complexes ◽  
Metal Bond ◽  
Metal Metal ◽  
Low Valent
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