Construction of Vicinal All-Carbon Quaternary Stereocenters by Catalytic Asymmetric Alkylation Reaction of 3-Bromooxindoles with 3-Substituted Indoles: Total Synthesis of (+)-Perophoramidine

2013 ◽  
Vol 135 (38) ◽  
pp. 14098-14101 ◽  
Author(s):  
Hailong Zhang ◽  
Liang Hong ◽  
Hong Kang ◽  
Rui Wang
Keyword(s):  
Total Synthesis ◽  
Alkylation Reaction ◽  
Asymmetric Alkylation ◽  
Catalytic Asymmetric ◽  
Quaternary Stereocenters

scholarly journals Highly Enantioselective Construction of Quaternary Stereocenters onβ-Keto Esters by Phase-Transfer Catalytic Asymmetric Alkylation and Michael Reaction

2003 ◽  
Vol 115 (34) ◽  
pp. 4111-4111 ◽  
Author(s):  
Takashi Ooi ◽  
Takashi Miki ◽  
Mika Taniguchi ◽  
Misato Shiraishi ◽  
Mifune Takeuchi ◽  
...  
Keyword(s):  
Michael Reaction ◽  
Phase Transfer ◽  
Asymmetric Alkylation ◽  
Keto Esters ◽  
Catalytic Asymmetric ◽  
Quaternary Stereocenters

scholarly journals Applications of oxazolidinones as chiral auxiliaries in the asymmetric alkylation reaction applied to total synthesis

RSC Advances ◽  
2016 ◽  
Vol 6 (36) ◽  
pp. 30498-30551 ◽  
Author(s):  
Majid M. Heravi ◽  
Vahideh Zadsirjan ◽  
Behnaz Farajpour
Keyword(s):  
Total Synthesis ◽  
Alkylation Reaction ◽  
Chiral Auxiliaries ◽  
Asymmetric Alkylation

In this review, a number of applications of chiral oxazolidinones in the asymmetric alkylation reaction applied to total synthesis are described.

Highly Enantioselective Construction of Quaternary Stereocenters onβ-Keto Esters by Phase-Transfer Catalytic Asymmetric Alkylation and Michael Reaction

2003 ◽  
Vol 115 (32) ◽  
pp. 3926-3928 ◽  
Author(s):  
Takashi Ooi ◽  
Takashi Miki ◽  
Mika Taniguchi ◽  
Misato Shiraishi ◽  
Mifune Takeuchi ◽  
...  
Keyword(s):  
Michael Reaction ◽  
Phase Transfer ◽  
Asymmetric Alkylation ◽  
Keto Esters ◽  
Catalytic Asymmetric ◽  
Quaternary Stereocenters
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