Modulating the σ-Accepting Properties of an Antimony Z-type Ligand via Anion Abstraction: Remote-Controlled Reactivity of the Coordinated Platinum Atom

2018 ◽  
Vol 140 (30) ◽  
pp. 9644-9651 ◽  
Author(s):  
Di You ◽  
Haifeng Yang ◽  
Srobona Sen ◽  
François P. Gabbaï
Keyword(s):  
Platinum Atom

The molecular and crystal structure of [Pt(diethylenetriamine)(guanosine)](ClO4)2

1979 ◽  
Vol 57 (1) ◽  
pp. 57-61 ◽  
Author(s):  
R. Melanson ◽  
F. D. Rochon
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Least Squares ◽  
Platinum Atom ◽  
X Ray Diffraction ◽  
Orthorhombic Space Group ◽  
X Ray ◽  
R Factor ◽  
Square Planar ◽  
Coordination Plane

The crystal structure of [Pt(diethylenetriamine)(guanosine)](ClO4)2 has been determined by X-ray diffraction. The crystals are orthorhombic, space group P212121, with a = 12.486(6), b = 13.444(7), c = 14.678(11) Å, and Z = 4. The structure was refined by block-diagonal least-squares analysis to a conventional R factor of 0.050 and a weighted Rw = 0.045.The coordination around the platinum atom is square planar. Guanosine is bonded to platinum through N(7). The purine planar ring makes an angle of 62.7° with the platinum coordination plane. The structure is stabilized by hydrogen bonding.

Atomic and molecular adsorption on single platinum atom at the graphene edge: A density functional theory study

2020 ◽  
Vol 152 (10) ◽  
pp. 104707
Author(s):  
Sasfan Arman Wella ◽  
Yuji Hamamoto ◽  
Ferry Iskandar ◽  
Suprijadi ◽  
Yoshitada Morikawa ◽  
...  
Keyword(s):  
Density Functional Theory ◽  
Density Functional ◽  
Platinum Atom ◽  
Molecular Adsorption ◽  
Density Functional Theory Study ◽  
Functional Theory ◽  
Graphene Edge

A tri-platinum complex containing a coordinatively naked platinum atom

Nature ◽  
1990 ◽  
Vol 344 (6266) ◽  
pp. 526-528 ◽  
Author(s):  
T. Tanase ◽  
Y. Kudo ◽  
M. Ohno ◽  
K. Kobayashi ◽  
Y. Yamamoto
Keyword(s):  
Platinum Complex ◽  
Platinum Atom

Diffusion of a Single Platinum Atom on Light-Element-Doped Graphene

2017 ◽  
Vol 121 (33) ◽  
pp. 17787-17795 ◽  
Author(s):  
Shun Hasegawa ◽  
Yuji Kunisada ◽  
Norihito Sakaguchi
Keyword(s):  
Light Element ◽  
Platinum Atom ◽  
Doped Graphene

Studies on the one-dimensional platinum atom chain compound Rb3(H3O)0.2[Pt(CN)4](O3SO·H·OSO3)0.5·0.8H2O

1987 ◽  
Vol 20 (3) ◽  
pp. 281-287
Author(s):  
Barry Kaye ◽  
Allan E. Underhill ◽  
Kim Carneiro ◽  
Kell Mortensen
Keyword(s):  
Platinum Atom ◽  
One Dimensional ◽  
Atom Chain ◽  
The One ◽  
Chain Compound

The crystal structure of potassium trichloro(2,6-lutidine)platinum(II)

1976 ◽  
Vol 54 (6) ◽  
pp. 1002-1006 ◽  
Author(s):  
R. Melanson ◽  
F. D. Rochon
Keyword(s):  
Crystal Structure ◽  
Complex Salt ◽  
Platinum Atom ◽  
Potassium Ions ◽  
Distorted Tetrahedron ◽  
X Ray Diffraction ◽  
Full Matrix ◽  
X Ray ◽  
Salt Forms ◽  
Coordination Plane

The molecular and crystal structure of potassium trichloro(2,6-lutidine)platinum(II) has been determined by X-ray diffraction. The complex salt forms monoclinic crystals, a = 6.941, b = 24.301, c = 11.168 Å, β = 141.58°, Z = 4, and space group P21/c. Positional and anisotropic thermal parameters were refined by full matrix least squares calculations to R = 0.038 and Rw = 0.034.The coordination around the platinum atom is planar. The Pt—Cl bond lengths are 2.301, 2.299, and 2.302 Å and the Pt—N bond length is 2.011 Å. The 2,6-lutidine ring lies almost perpendicular to the coordination plane of the platinum atom (81.6°). The PtCl3 moieties are packed around the potassium ions, which are surrounded by four chlorine atoms at distances smaller than 3.15 Å forming a distorted tetrahedron.

Tetramethyld-η2-vinyldisiloxan(triphenylphosphan)platin(0) / Tetramethyldi-η2-vinyldisiloxane(triphenylphosphine)platinum(0)

1991 ◽  
Vol 46 (12) ◽  
pp. 1694-1698 ◽  
Author(s):  
Georg Beuter ◽  
Olga Heyke ◽  
Ingo-Peter Lorenz
Keyword(s):  
Crystal Structure ◽  
Chair Conformation ◽  
Ring System ◽  
Platinum Atom ◽  
X Ray Diffraction ◽  
Space Group ◽  
X Ray

The reaction of (Ph3P)2PtC2H4 with the divinyldisiloxane (CH2=CHSiMe2)2O in toluene yields Pt{(η2-H2C=CHSiMe2)2O}PPh3, which has been characterized by IR, 1H, 13C, 31P NMR and MS spectra. The crystal structure was determined by X-ray diffraction: space group C2/c, Z = 16, a = 5534.2(9), b = 842.6(2), c = 2383.1(2) pm, β = 103.73(1)°, R/Rw = 0.047/0.052. It shows a three-coordinate platinum atom with one phosphine and one sym-tetramethyldivinyldisiloxane ligand acting as a chelating bidentate η/2-ligand to give a chair conformation of the six-membered PtC2Si2O-ring system.

The Crystal Structure of cis-Dichloro(2,2′-oxydi-3-butene)platinum(II), PtCl2((CH2=CH—CH(CH3))2O)

1973 ◽  
Vol 51 (4) ◽  
pp. 604-608 ◽  
Author(s):  
J. Hubert ◽  
A. L. Beauchamp ◽  
T. Theophanides
Keyword(s):  
Crystal Structure ◽  
Least Squares ◽  
Platinum Atom ◽  
Double Bonds ◽  
Triclinic Space Group ◽  
Standard Methods ◽  
Full Matrix ◽  
R Factor ◽  
Square Planar ◽  
Coordination Plane

The reaction of K2PtCl4 with CH3—CH=CH—CH2—OH yields the complex cis-[PtCl2((CH2=CH—CH(CH3))2O)]. The crystals are triclinic, space group [Formula: see text], a = 9.420(2) Å, b = 8.359(4) Å, c = 7.837(4) Å, α = 91.10(4)°, β = 62.13(4)°, γ = 80.80(5)°, and Z = 2. The structure, solved by standard methods, has been refined anisotropically by full matrix least-squares methods to a R factor of 0.052 by use of 2441 independent observed reflections. The complex is a monomer, where both double bonds of the diolefin ether are coordinated to the platinum atom as in Zeise's salt. The usual square planar coordination of platinum(II) is completed by two chlorine atoms. The (=CH2) groups of both double bonds are found on the same side of the coordination plane. Various possible conformations of the coordinated ligand in the complex are discussed.

Chemistry of vinylidene complexes X. Synthesis and characterization of the vinylidene bridged complexes Cp(CO)2MnPt(μ-CCHPh)(PP) with chelating diphosphine ligands PPdppm, dppe or dppp at the platinum atom

1991 ◽  
Vol 182 (1) ◽  
pp. 49-54 ◽  
Author(s):  
Alla B. Antonova ◽  
Svetlana V. Kovalenko ◽  
Alfred A. Johansson ◽  
Evgeny D. Korniyets ◽  
Irina A. Sukhina ◽  
...  
Keyword(s):  
Platinum Atom ◽  
Synthesis And Characterization ◽  
Diphosphine Ligands ◽  
Vinylidene Complexes

Metallaborane Reaction Chemistry. Part 7. B-Frame Supported Bimetallics: Ligand-to-β-Metal Organometallic Interaction in Dimetallaboranes and an Interesting Ligand Displacement Cascade

1999 ◽  
Vol 64 (6) ◽  
pp. 938-946 ◽  
Author(s):  
Young-hee Kim ◽  
Yvonne M. McKinnes ◽  
Paul A. Cooke ◽  
Robert Greatrex ◽  
John D. Kennedy ◽  
...  
Keyword(s):  
Metal Atom ◽  
Phenyl Group ◽  
Phosphine Ligand ◽  
Platinum Atom ◽  
Displacement Cascade ◽  
Ligand Displacement

Reaction of [PtCl2(PMe2Ph)2] with [(PMe2Ph)2PtB10H12] generates [(PMe2Ph)2-μ-η1(Pt)- η1-(Pt')-{PMe2(C6H4)}-closo-Pt2B10H9(PMe2Ph)] in which the phenyl group of a phosphine ligand on one platinum atom exhibits ortho-cyclometallation to the second metal atom, whereas reaction of PPh3 with [(PMe2Ph)2PtB9H9Ru(pcym)] generates [(PMe2Ph)2-μ-η6(Ru)- η1(Pt)-(C6H5PPh2)-closo-PtRuB9H9] in which the phenyl group of a phosphine ligand on the platinum atom exhibits tridentate η6 coordination to the second metal atom.

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