Scope of Stereoselective Mn-Mediated Radical Addition to Chiral Hydrazones and Application in a Formal Synthesis of Quinine

2012 ◽  
Vol 77 (7) ◽  
pp. 3159-3180 ◽  
Author(s):  
Gregory K. Friestad ◽  
An Ji ◽  
Jonas Baltrusaitis ◽  
Chandra Sekhar Korapala ◽  
Jun Qin
Keyword(s):  
Radical Addition ◽  
Formal Synthesis

A Formal Synthesis of Camptothecin via a Photocatalytic Decarboxylative Radical Addition

2019 ◽  
Vol 2019 (35) ◽  
pp. 6024-6027 ◽  
Author(s):  
Qian Liu ◽  
Guanxin Huang ◽  
Minjie Liu ◽  
Fener Chen
Keyword(s):  
Radical Addition ◽  
Formal Synthesis

Development of radical addition–cyclization–elimination reaction of oxime ether and its application to formal synthesis of (±)-martinelline

Tetrahedron ◽  
2007 ◽  
Vol 63 (40) ◽  
pp. 10092-10117 ◽  
Author(s):  
Okiko Miyata ◽  
Atsushi Shirai ◽  
Shintaro Yoshino ◽  
Toshiki Nakabayashi ◽  
Yoshifumi Takeda ◽  
...  
Keyword(s):  
Radical Addition ◽  
Elimination Reaction ◽  
Oxime Ether ◽  
Formal Synthesis

scholarly journals Regioselective Radical Alkene Amination Strategies by Using Phosphite-Mediated Deoxygenation

Synlett ◽  
2019 ◽  
Vol 30 (18) ◽  
pp. 2022-2026
Author(s):  
Samuel W. Lardy ◽  
Valerie A. Schmidt
Keyword(s):  
Radical Addition ◽  
Primary Amines ◽  
Efficient Synthesis ◽  
Formal Synthesis ◽  
Group Transfer ◽  
Radical Group ◽  
Nitrogen Containing Compounds

Nitrogen-containing compounds are an essential motif in all disciplines of chemistry and the efficient synthesis of these frameworks is a highly sought-after goal. Presented here is a summary of recent efforts conducted by our group to develop radical-mediated amination strategies for the formal synthesis of primary amines from alkenes with exclusive anti-Markovnikov regioselectivity. We have found that N-hydroxyphthalimide is an effective reagent capable of supplying both the N and H atoms for alkene hydroamination in a group transfer radical addition-type mechanism. Furthermore, allyl-oxyphthalimide derivatives are similarly capable of radical group transfers and allow for the aminoallylation of an external alkene.

ChemInform Abstract: A Formal Synthesis of (+)-α-Allokainic Acid via Sulfanyl Radical Addition-Cyclization Reaction.

ChemInform ◽  
2010 ◽  
Vol 29 (16) ◽  
pp. no-no
Author(s):  
O. MIYATA ◽  
Y. OZAWA ◽  
I. NINOMIYA ◽  
K. AOE ◽  
H. HIRAMATSU ◽  
...  
Keyword(s):  
Radical Addition ◽  
Cyclization Reaction ◽  
Formal Synthesis

A Formal Synthesis of (±)-Tylophorine Based on an Atom Transfer Radical Addition Reaction

Synlett ◽  
2013 ◽  
Vol 24 (16) ◽  
pp. 2073-2076 ◽  
Author(s):  
Alejandro Cordero-Vargas ◽  
Ever Blé-González ◽  
Susana Porcel
Keyword(s):  
Addition Reaction ◽  
Radical Addition ◽  
Atom Transfer ◽  
Formal Synthesis ◽  
Atom Transfer Radical Addition

A Formal Synthesis of (+)-a-Allokainic Acid via Sulfanyl Radical Addition-Cyclization Reaction

Heterocycles ◽  
1997 ◽  
Vol 46 (1) ◽  
pp. 321 ◽  
Author(s):  
Takeaki Naito ◽  
Okiko Miyata ◽  
Yoshiki Ozawa ◽  
Ichiya Ninomiya ◽  
Keiichi Aoe ◽  
...  
Keyword(s):  
Radical Addition ◽  
Cyclization Reaction ◽  
Formal Synthesis
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