atom transfer
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Effect of atom transfer radical polymerization reaction time on PCB binding capacities of Styrene-CMA/QMA Core-Shell iron oxide nanoparticles

2022 ◽  
Vol 277 ◽  
pp. 115577
Author(s):  
Angela M. Gutierrez ◽  
Francisco C. Leniz ◽  
Xinya Wang ◽  
Thomas D. Dziubla ◽  
J. Zach Hilt
Keyword(s):  
Iron Oxide ◽  
Reaction Time ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Iron Oxide Nanoparticles ◽  
Polymerization Reaction ◽  
Oxide Nanoparticles ◽  
Core Shell ◽  
Atom Transfer

Photoredox Polyfluoroarylation of Alkyl Halides via Halogen Atom Transfer

2022 ◽  
Author(s):  
Ben Niu ◽  
Krishnakumar Sachidanandan ◽  
Bryan G. Blackburn ◽  
Maria Victoria Cooke ◽  
Sébastien Laulhé
Keyword(s):  
Halogen Atom ◽  
Alkyl Halides ◽  
Atom Transfer

Photoinduced C-H monofluoroalkenylation with gem-difluoroalkenes through hydrogen atom transfer in batch and flow

2022 ◽  
Author(s):  
Chen-Lin Cao ◽  
Guang-Xu Zhang ◽  
Fei Xue ◽  
Hong-Ping Deng
Keyword(s):  
Hydrogen Atom ◽  
Hydrogen Atom Transfer ◽  
Atom Transfer

Direct monofluoroalkenylation of C-H bonds are straightforward approaches for accessing multisubstituted monofluoroalkenes. However, general methods for the monofluoroalkenylation of C(sp3)-H bonds remain challenges. Here we report the development of a...

scholarly journals Hydrogen-atom and oxygen-atom transfer reactivities of iron(iv)-oxo complexes of quinoline-substituted pentadentate ligands

2022 ◽  
Author(s):  
Sandip Munshi ◽  
Arup Sinha ◽  
Solomon Yiga ◽  
Sridhar Banerjee ◽  
Reena Singh ◽  
...  
Keyword(s):  
Hydrogen Atom ◽  
Oxygen Atom ◽  
Electronic Properties ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxo Complexes ◽  
Pentadentate Ligands

The reactivities of Fe(iv) oxido complexes of two pentadentate ligands are related to steric and electronic properties of the ligands.

Stereodivergent atom-transfer radical cyclization by engineered cytochromes P450

Science ◽  
2021 ◽  
Vol 374 (6575) ◽  
pp. 1612-1616 ◽  
Author(s):  
Qi Zhou ◽  
Michael Chin ◽  
Yue Fu ◽  
Peng Liu ◽  
Yang Yang
Keyword(s):  
Cytochromes P450 ◽  
Radical Cyclization ◽  
Atom Transfer ◽  
Atom Transfer Radical Cyclization

scholarly journals SOMOphilic Alkynylation of Unreactive Alkenes Enabled by Iron-Catalyzed Hydrogen Atom Transfer

Molecules ◽  
2021 ◽  
Vol 27 (1) ◽  
pp. 33
Author(s):  
Binlin Zhao ◽  
Tianxiang Zhu ◽  
Mengtao Ma ◽  
Zhuangzhi Shi
Keyword(s):  
Hydrogen Atom ◽  
Hydrogen Atom Transfer ◽  
Catalytic Cycle ◽  
Atom Transfer ◽  
Iron Hydride ◽  
Internal Alkynes ◽  
Hydride Hydrogen ◽  
Transfer Protocol ◽  
Acetylenic Sulfones

We report an efficient and practical iron-catalyzed hydrogen atom transfer protocol for assembling acetylenic motifs into functional alkenes. Diversities of internal alkynes could be obtained from readily available alkenes and acetylenic sulfones with excellent Markovnikov selectivity. An iron hydride hydrogen atom transfer catalytic cycle was described to clarify the mechanism of this reaction.

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