New General Method for Regio- and Stereoselective Allylic Substitution with Aryl and Alkenyl Coppers Derived from Grignard Reagents

2009 ◽  
Vol 74 (5) ◽  
pp. 1939-1951 ◽  
Author(s):  
Yohei Kiyotsuka ◽  
Yuji Katayama ◽  
Hukum P. Acharya ◽  
Tomonori Hyodo ◽  
Yuichi Kobayashi
Keyword(s):  
Grignard Reagents ◽  
Allylic Substitution ◽  
General Method

ChemInform Abstract: New General Method for Regio- and Stereoselective Allylic Substitution with Aryl and Alkenyl Coppers Derived from Grignard Reagents.

ChemInform ◽  
2009 ◽  
Vol 40 (29) ◽  
Author(s):  
Yohei Kiyotsuka ◽  
Yuji Katayama ◽  
Hukum P. Acharya ◽  
Tomonori Hyodo ◽  
Yuichi Kobayashi
Keyword(s):  
Grignard Reagents ◽  
Allylic Substitution ◽  
General Method

Sequential Copper-Catalyzed Rearrangement-Allylic Substitution of Bicyclic Hydrazines with Grignard Reagents

2009 ◽  
Vol 351 (6) ◽  
pp. 869-873 ◽  
Author(s):  
Stefano Crotti ◽  
Ferruccio Bertolini ◽  
Franco Macchia ◽  
Mauro Pineschi
Keyword(s):  
Grignard Reagents ◽  
Allylic Substitution

scholarly journals Allylic Substitution Reactions with Grignard Reagents Catalyzed by Imidazolium and 4,5-Dihydroimidazolium Carbene—CuCl Complexes.

ChemInform ◽  
2006 ◽  
Vol 37 (29) ◽  
Author(s):  
Sentaro Okamoto ◽  
Satoshi Tominaga ◽  
Naoko Saino ◽  
Kouki Kase ◽  
Kentaro Shimoda
Keyword(s):  
Grignard Reagents ◽  
Allylic Substitution ◽  
Substitution Reactions

Iron-Catalyzed Grignard Cross-Couplings with Allylic Methyl Ethers or Allylic Trimethylsilyl Ethers

Synlett ◽  
2018 ◽  
Vol 29 (09) ◽  
pp. 1211-1214 ◽  
Author(s):  
Chika Seto ◽  
Takeshi Otsuka ◽  
Yoshiki Takeuchi ◽  
Daichi Tabuchi ◽  
Takashi Nagano
Keyword(s):  
Cross Coupling ◽  
Grignard Reagents ◽  
Allylic Substitution ◽  
Trimethylsilyl Ethers

We have found that cross-coupling between aryl Grignard reagents and allylic methyl ethers proceeded well in the presence of a catalytic amounts of Fe(acac)3 to afford the corresponding allylic substitution products in good yields. Under the same conditions, allylic trimethylsilyl ethers also reacted with Grignard reagents to give the corresponding cross-coupling products.

Cobalt-Catalyzed Allylic Substitution Reaction of Allylic Ethers with Phenyl and Trimethylsilylmethyl Grignard Reagents

2004 ◽  
Vol 33 (7) ◽  
pp. 832-833 ◽  
Author(s):  
Keiya Mizutani ◽  
Hideki Yorimitsu ◽  
Koichiro Oshima
Keyword(s):  
Substitution Reaction ◽  
Grignard Reagents ◽  
Allylic Substitution ◽  
Allylic Ethers

A general method for the direct transformation of common tertiary amides into ketones and amines by addition of Grignard reagents

Tetrahedron ◽  
2015 ◽  
Vol 71 (24) ◽  
pp. 4248-4254 ◽  
Author(s):  
Pei-Qiang Huang ◽  
Yu Wang ◽  
Kai-Jiong Xiao ◽  
Ying-Hong Huang
Keyword(s):  
Grignard Reagents ◽  
Direct Transformation ◽  
Tertiary Amides ◽  
General Method

ChemInform Abstract: Allylic Substitution of 4-Cyclopentene-1,3-diol Monoacetate with Copper Reagents Derived from Functionalized Aryl Grignard Reagents.

ChemInform ◽  
2010 ◽  
Vol 41 (22) ◽  
pp. no-no
Author(s):  
Yuichi Kobayashi ◽  
Yukio Tani ◽  
Kenya Nakata ◽  
Yuki Kaneko
Keyword(s):  
Grignard Reagents ◽  
Allylic Substitution

Cu-Catalyzed Enantioselective Allylic Substitution with Grignard Reagents

Synfacts ◽  
2006 ◽  
Vol 2006 (04) ◽  
pp. 0372-0372
Keyword(s):  
Grignard Reagents ◽  
Allylic Substitution

General Method of Synthesis for Naloxone, Naltrexone, Nalbuphone, and Nalbuphine by the Reaction of Grignard Reagents with an Oxazolidine Derived from Oxymorphone

2013 ◽  
Vol 355 (9) ◽  
pp. 1869-1873 ◽  
Author(s):  
Mary Ann A. Endoma-Arias ◽  
D. Phillip Cox ◽  
Tomas Hudlicky
Keyword(s):  
Grignard Reagents ◽  
General Method
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