Factors Affecting In-Plane and Out-of-Plane Photoorientation of Azobenzene Side Chains Attached to Liquid Crystalline Polymers Induced by Irradiation with Linearly Polarized Light

2000 ◽  
Vol 33 (17) ◽  
pp. 6360-6371 ◽  
Author(s):  
Mina Han ◽  
Shin'ya Morino ◽  
Kunihiro Ichimura
Author(s):  
Christine M. Dannels ◽  
Christopher Viney

Processing polymers from the liquid crystalline state offers several advantages compared to processing from conventional fluids. These include: better axial strength and stiffness in fibers, better planar orientation in films, lower viscosity during processing, low solidification shrinkage of injection moldings (thermotropic processing), and low thermal expansion coefficients. However, the compressive strength of the solid is disappointing. Previous efforts to improve this property have focussed on synthesizing stiffer molecules. The effect of microstructural scale has been overlooked, even though its relevance to the mechanical and physical properties of more traditional materials is well established. By analogy with the behavior of metals and ceramics, one would expect a fine microstructure (i..e. a high density of orientational defects) to be desirable.Also, because much microstructural detail in liquid crystalline polymers occurs on a scale close to the wavelength of light, light is scattered on passing through these materials.


2021 ◽  
Author(s):  
Shuqi Dai ◽  
Jinxing Li ◽  
Junichi Kougo ◽  
Huanyu Lei ◽  
Satoshi Aya ◽  
...  

2007 ◽  
Vol 40 (26) ◽  
pp. 9361-9370 ◽  
Author(s):  
Chun-Peng Chai ◽  
Xing-Qi Zhu ◽  
Ping Wang ◽  
Min-Qiao Ren ◽  
Xiao-Fang Chen ◽  
...  

Author(s):  
David Lacey ◽  
Alan W. Hall ◽  
Peter N. Lavrenko ◽  
Natalia P. Yevlampieva ◽  
Olga V. Okatova ◽  
...  

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