Regio- and Stereoselective Synthesis of 2-Deoxy-C-aryl Glycosides via Palladium Catalyzed Decarboxylative Reactions

2011 ◽  
Vol 13 (17) ◽  
pp. 4608-4611 ◽  
Author(s):  
Shaohua Xiang ◽  
Shuting Cai ◽  
Jing Zeng ◽  
Xue-Wei Liu
Keyword(s):  
Stereoselective Synthesis ◽  
Palladium Catalyzed ◽  
Aryl Glycosides

Highly regioselective and stereoselective synthesis of C-Aryl glycosides via Nickel-catalyzed ortho-C-H glycosylation of 8-aminoquinoline benzamides

2021 ◽  
Author(s):  
Wei-Yu Shi ◽  
Ya-Nan Ding ◽  
Nian Zheng ◽  
Xue-Ya Gou ◽  
Zhe Zhang ◽  
...  
Keyword(s):  
Stereoselective Synthesis ◽  
Cost Effective ◽  
Drug Candidates ◽  
Aryl Glycosides ◽  
Glycosylation Reaction

C-Aryl glycosides are of high value as drug candidates. Here a novel and cost-effective nickel catalyzed ortho-CAr-H glycosylation reaction with high regioselectivity and excellent α-selectivity is described. This method shows...

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