Oxidative Addition of MeI to a Rhodium(I) N-Heterocyclic Carbene Complex. A Kinetic Study

2003 ◽  
Vol 22 (22) ◽  
pp. 4451-4458 ◽  
Author(s):  
Helen C. Martin ◽  
Neil H. James ◽  
John Aitken ◽  
Joseph A. Gaunt ◽  
Harry Adams ◽  
...  
Keyword(s):  
Kinetic Study ◽  
Oxidative Addition ◽  
Carbene Complex

On the Reactivity of mRNA Caps: C-H Oxidative Addition of 7-Methylguanosine to Pt(0)

2019 ◽  
Author(s):  
Maria Ines Leitao ◽  
Carmen Gonzalez ◽  
Zuzanna Filipiak ◽  
Ana Petronilho
Keyword(s):  
Oxidative Addition ◽  
Carbene Complex ◽  
Proton Loss

<p>7-methylguanosine, the so-called mRNA cap 0 bears a very labile C8-H bond, due to the formation of an ylide/N-heterocyclic carbene, upon proton loss. The reaction of 7-methylguanosine with Pt(PPh3)4, via C-H oxidative addition, yields a hydrido–PtII carbene complex and this reactivity can be extrapolated to 7,9-dimethylguanine. </p>

Thermodynamic and Kinetic Study of Oxidative Addition/Reductive Elimination of H2and D2to FulvaleneCr2(CO)6:  Evidence for Relatively Strong Metal−Metal Bonds in Fulvalenedimetals

1999 ◽  
Vol 38 (11) ◽  
pp. 2624-2631 ◽  
Author(s):  
K. Peter C. Vollhardt ◽  
J. Kevin Cammack ◽  
Adam J. Matzger ◽  
Andreas Bauer ◽  
Kenneth B. Capps ◽  
...  
Keyword(s):  
Kinetic Study ◽  
Oxidative Addition ◽  
Reductive Elimination ◽  
Metal Metal ◽  
Metal Metal Bonds ◽  
Metal Bonds

Oxidative Addition of Methyl Iodide to a New Type of Binuclear Platinum(II) Complex:  a Kinetic Study

2005 ◽  
Vol 44 (23) ◽  
pp. 8594-8601 ◽  
Author(s):  
Sirous Jamali ◽  
S. Masoud Nabavizadeh ◽  
Mehdi Rashidi
Keyword(s):  
Kinetic Study ◽  
Methyl Iodide ◽  
Oxidative Addition ◽  
New Type

Kinetic study of the oxidative addition of methyl iodide to Vaska’s complex in ionic liquids

2005 ◽  
Vol 690 (15) ◽  
pp. 3522-3528 ◽  
Author(s):  
Steven J. P’Pool ◽  
Marc A. Klingshirn ◽  
Robin D. Rogers ◽  
Kevin H. Shaughnessy
Keyword(s):  
Ionic Liquids ◽  
Kinetic Study ◽  
Methyl Iodide ◽  
Oxidative Addition ◽  
Vaska's Complex

On the Reactivity of mRNA Caps: C-H Oxidative Addition of 7-Methylguanosine to Pt(0)

2019 ◽  
Author(s):  
Maria Ines Leitao ◽  
Carmen Gonzalez ◽  
Zuzanna Filipiak ◽  
Ana Petronilho
Keyword(s):  
Oxidative Addition ◽  
Carbene Complex ◽  
Proton Loss

<p>7-methylguanosine, the so-called mRNA cap 0 bears a very labile C8-H bond, due to the formation of an ylide/N-heterocyclic carbene, upon proton loss. The reaction of 7-methylguanosine with Pt(PPh3)4, via C-H oxidative addition, yields a hydrido–PtII carbene complex and this reactivity can be extrapolated to 7,9-dimethylguanine. </p>

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