Synthesis of open metal carbonyl cluster compounds. The reactions of closo-sulfido metal carbonyl cluster compounds with hydrogen sulfide. Synthesis and crystal and molecular structure of H2Os5(CO)14(.mu.3-S)2

Metal Carbonyl ◽

Cluster Compounds ◽

Carbonyl Cluster ◽

ChemInform Abstract: UNUSUAL METAL-METAL BONDING IN TRANSITION-METAL CARBONYL CLUSTER COMPOUNDS. THE SYNTHESIS, REACTIVITY, AND CRYSTAL AND MOLECULAR STRUCTURE OF BIS(DI-μ3-SULFIDO-OCTACARBONYLTRIOSMIUM) ((OS3(CO)8(μ3-S)2)2)

Chemischer Informationsdienst ◽

10.1002/chin.198426315 ◽

1984 ◽

Vol 15 (26) ◽

Author(s):

R. D. ADAMS ◽

I. T. HORVATH

Keyword(s):

Molecular Structure ◽

Transition Metal ◽

Metal Carbonyl ◽

Cluster Compounds ◽

Carbonyl Cluster ◽

Metal Bonding ◽

Metal Metal ◽

Unusual metal-metal bonding in transition-metal carbonyl cluster compounds. The synthesis, reactivity, and crystal and molecular structure of bis(di-.mu.3-sulfido-octacarbonyltriosmium) ([Os3(CO)8(.mu.3-S)2]2)

Journal of the American Chemical Society ◽

10.1021/ja00318a070 ◽

1984 ◽

Vol 106 (6) ◽

pp. 1869-1871 ◽

Cited By ~ 20

Author(s):

Richard D. Adams ◽

Istvan T. Horvath

Keyword(s):

Molecular Structure ◽

Transition Metal ◽

Metal Carbonyl ◽

Cluster Compounds ◽

Carbonyl Cluster ◽

Metal Bonding ◽

Metal Metal ◽

Cluster synthesis. 3. The role of sulfido ligands in the synthesis of high nuclearity metal carbonyl cluster compounds. The crystal and molecular structure of Os4(CO)12(.mu.3-S) and Os7(CO)19(.mu.4-S)

Organometallics ◽

10.1021/om50002a009 ◽

1983 ◽

Vol 2 (8) ◽

pp. 990-996 ◽

Cited By ~ 20

Author(s):

Richard D. Adams ◽

Donald F. Foust ◽

Pradeep Mathur

Keyword(s):

Molecular Structure ◽

Metal Carbonyl ◽

Cluster Compounds ◽

Carbonyl Cluster ◽

Cluster synthesis. 4. The role of sulfido ligands in the synthesis of high nuclearity metal carbonyl cluster compounds. The synthesis of Os4(CO)13(.mu.3-S)2 and Os7(CO)20(.mu.4-S)2 and the crystal and molecular structure of Os7(CO)20(.mu.4-S)2

Organometallics ◽

10.1021/om50003a003 ◽

1983 ◽

Vol 2 (9) ◽

pp. 1078-1083 ◽

Cited By ~ 22

Author(s):

Richard D. Adams ◽

Istvan T. Horvath ◽

Pradeep Mathur ◽

Brigitte E. Segmueller ◽

Li Wu Yang

Keyword(s):

Molecular Structure ◽

Metal Carbonyl ◽

Cluster Compounds ◽

Carbonyl Cluster ◽

An unusual example of intramolecular hydrogen bonding in a metal carbonyl cluster compound. Synthesis and crystal and molecular structure of di-.mu.-carbonylhexadecacarbonyldi-.mu.-hydroxo-.mu.4-sulfidohexaruthenium

Inorganic Chemistry ◽

10.1021/ic00262a046 ◽

1987 ◽

Vol 26 (15) ◽

pp. 2561-2563 ◽

Cited By ~ 11

Author(s):

Richard D. Adams ◽

James E. Babin ◽

Miklos Tasi

Keyword(s):

Molecular Structure ◽

Hydrogen Bonding ◽

Metal Carbonyl ◽

Intramolecular Hydrogen Bonding ◽

Cluster Compound ◽

Carbonyl Cluster ◽

Compound Synthesis ◽

Intramolecular Hydrogen ◽

ChemInform Abstract: An Unusual Example of Intramolecular Hydrogen Bonding in a Metal Carbonyl Cluster Compound. Synthesis and Crystal and Molecular Structure of Ru6(CO)16(μ-CO)2(μ-OH)2(μ4-S).

ChemInform ◽

10.1002/chin.198747294 ◽

1987 ◽

Vol 18 (47) ◽

Author(s):

R. D. ADAMS ◽

J. E. BABIN ◽

M. TASI

Keyword(s):

Molecular Structure ◽

Hydrogen Bonding ◽

Metal Carbonyl ◽

Intramolecular Hydrogen Bonding ◽

Cluster Compound ◽

Carbonyl Cluster ◽

Compound Synthesis ◽

Intramolecular Hydrogen ◽

The vibrations of bridging carbonyl groups as more sensitive indicators of molecular geometry than terminal carbonyl groups in transition metal carbonyl cluster compounds

Inorganica Chimica Acta ◽

10.1016/0020-1693(94)04216-0 ◽

1994 ◽

Vol 227 (2) ◽

pp. 241-246 ◽

Cited By ~ 2

Author(s):

S.F.A. Kettle ◽

E. Diana ◽

R. Rossetti ◽

P.L. Stanghellini ◽

R. Della Pergola ◽

...

Keyword(s):

Transition Metal ◽

Metal Carbonyl ◽

Molecular Geometry ◽

Cluster Compounds ◽

Carbonyl Cluster ◽

Carbonyl Groups ◽

Synthesis of sulfidoosmium carbonyl cluster compounds by the photochemical decomposition of .mu.-(phenylthio)decacarbonylhydridotriosmium [HOs3(CO)10(.mu.-SPh)] and its subsequent reactions with selected small molecules. Synthesis and crystal and molecular structure of (.mu.3-sulfido)(.mu.3-carbonyl)nonacarbonyltriosmium [Os3(CO)9(.mu.3-CO)(.mu.3-S)]

Organometallics ◽

10.1021/om00082a006 ◽

1984 ◽

Vol 3 (4) ◽

pp. 548-552 ◽

Cited By ~ 29

Author(s):

Richard D. Adams ◽

Istvan T. Horvath ◽

Hoon Sik Kim

Keyword(s):

Molecular Structure ◽

Small Molecules ◽

Cluster Compounds ◽

Carbonyl Cluster ◽

Photochemical Decomposition

ChemInform Abstract: CLUSTER SYNTHESES. 2. THE ROLE OF HETEROATOMS IN THE FORMATION OF HIGH NUCLEARITY TRANSITION-METAL CARBONYL CLUSTER COMPOUNDS. THE CONDENSATION OF SMALL CLUSTERS

Chemischer Informationsdienst ◽

10.1002/chin.198322315 ◽

1983 ◽

Vol 14 (22) ◽

Author(s):

R. D. ADAMS ◽

Z. DAWOODI ◽

D. F. FOUST ◽

B. E. SEGMUELLER

Keyword(s):

Transition Metal ◽

Metal Carbonyl ◽

Cluster Compounds ◽

Carbonyl Cluster ◽

Small Clusters ◽

Novel Reactions of Metal Carbonyl Cluster Compounds

Progress in Inorganic Chemistry ◽

10.1002/9780470166345.ch3 ◽

2007 ◽

pp. 127-181 ◽

Cited By ~ 49

Author(s):

Richard D. Adams ◽

István T. Horváth

Keyword(s):

Metal Carbonyl ◽

Cluster Compounds ◽

Carbonyl Cluster ◽