Reflection absorption IR studies of vibrational energy transfer processes and adsorption energetics

1997 ◽  
Vol 93 (13) ◽  
pp. 2315-2322 ◽  
Author(s):  
Jeanette C. Cook ◽  
Steven K. Clowes ◽  
Elaine M. McCash
1972 ◽  
Vol 50 (21) ◽  
pp. 2691-2697 ◽  
Author(s):  
W. G. Tam

The Sharma and Brau theory developed for the near-resonance vibrational energy transfer processes due to the Coulomb interaction between colliding molecules is shown to be valid also for processes which are far away from resonance. A modified Sharma and Brau theory valid for arbitrary energy discrepancy is described. For off-resonance vibrational energy transfer the head-on collisions are shown to play a dominant role.


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