Synthesis, spectroscopic and redox properties of ruthenium complexes with selenoether macrocycles: crystal structures of cis-[RuCl2([16]aneSe4)] and trans-[RuCl(PPh3)([16]aneSe4)]PF6 ([16]aneSe4 = 1,5,9,13-tetraselenacyclohexadecane)

Author(s):  
William Levason ◽  
Jeffrey J. Quirk ◽  
Gillian Reid ◽  
Stephen M. Smith



2000 ◽  
Vol 49 (3) ◽  
pp. 444-451 ◽  
Author(s):  
N. A. Sanina ◽  
I. I. Chuev ◽  
S. M. Aldoshin ◽  
N. S. Ovanesyan ◽  
V. V. Strelets ◽  
...  


2011 ◽  
Vol 50 (21) ◽  
pp. 10581-10591 ◽  
Author(s):  
Neus Vilà ◽  
Guy Royal ◽  
Frédérique Loiseau ◽  
Alain Deronzier






1993 ◽  
Vol 204 (2) ◽  
pp. 141-146 ◽  
Author(s):  
Michael R. McDevitt ◽  
Anthony W. Addison




2013 ◽  
Vol 68 (9) ◽  
pp. 993-999 ◽  
Author(s):  
Xiuli Wu ◽  
Rufei Ye ◽  
Ai-Quan Jia ◽  
Qun Chen ◽  
Qian-Feng Zhang

Treatment of Ru(acac)3 with 2-cyano-pyridine and 3,5-dimethyl-pyridine in the presence of zinc dust as reducing agent in refluxing THF afforded the ruthenium(II) complexes cis-[RuII(acac)2(2- CN-py)2] (1) and cis-[RuII(acac)2(3,5-Me2-py)2] (2), respectively. Interaction of Ru(acac)3 with 3- Me-pyridine and 3,5-Me2-pyridine in the presence of Br2 in refluxing THF gave the ruthenium(III) complexes [RuIII(acac)Br2(3-Me-py)2] (3) and [RuIII(acac)Br2(3,5-Me2-py)2] (4), respectively. The four complexes have been spectroscopically and electrochemically characterized, and their crystal and molecular structures have been established by X-ray crystallography



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