Observation of supramolecular π–π dimerization of a dinuclear ruthenium complex by 1H NMR and ESMS

1998 ◽  
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André Gourdon

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Takakazu Yamamoto ◽  
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The title compound,cis-di-μ-perfluoroheptanoato-κ4O:O′-bis[dicarbonyl(dimethyl sulfoxide-κS)ruthenium(I)](Ru—Ru), [Ru2(C7F13O2)2(C2H6OS)2(CO)4], is a sawhorse-type dinuclear ruthenium complex with two bridging perfluoroheptanoate ligands, and with two dimethyl sulfoxide (DMSO) ligands in the axial positions coordinatingviathe S atoms. It is a new example of a compound with an aliphatic fluorinated carboxylate ligand. The Ru—Ru bond distance of 2.6908 (3) Å indicates a direct Ru—Ru interaction. The compound is an active catalyst in transvinylation of propionic acid with vinyl acetate.



2010 ◽  
Vol 46 (35) ◽  
pp. 6506 ◽  
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Yunhua Xu ◽  
Lele Duan ◽  
Lianpeng Tong ◽  
Björn Åkermark ◽  
Licheng Sun


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