Electronic and photophysical properties of a novel phenol bound dinuclear ruthenium complex: evidence for a luminescent mixed valence stateElectronic supplementary information (ESI) available: Resonance Raman and ES MS spectra. See http://www.rsc.org/suppdata/dt/b4/b405114a/

2004 ◽  
pp. 2341 ◽  
Author(s):  
Tia E. Keyes ◽  
Benedicte Evrard ◽  
Johannes G. Vos ◽  
Clare Brady ◽  
John J. McGarvey ◽  
...  
Keyword(s):  
Ruthenium Complex ◽  
Photophysical Properties ◽  
Mixed Valence ◽  
Resonance Raman ◽  
Supplementary Information ◽  
Dinuclear Ruthenium

Mixed-valence properties of a dinuclear ruthenium complex bridged by bis(phenylcyanamido)tetrazine

2014 ◽  
Vol 92 (11) ◽  
pp. 1081-1085 ◽  
Author(s):  
Fatemeh Habibagahi ◽  
Robert J. Crutchley
Keyword(s):  
Ruthenium Complex ◽  
Mixed Valence ◽  
Transition Dipole Moment ◽  
The Novel ◽  
Transition Dipole ◽  
H Nmr ◽  
Bridging Ligand ◽  
Metal Metal ◽  
Dinuclear Ruthenium ◽  
The Stability

The novel bridging ligand 3,6-bis(phenylcyanamido)-1,2,4,5-tetrazine (tdpcH2) and its dinuclear complex [{Ru(ttpy)(bpy)}2(μ-tdpc)][PF6]2 were prepared and characterized by elemental analysis and 1H NMR spectroscopy. Cyclic voltammetry and vis-NIR and IR spectroelectrochemistry of [{Ru(ttpy)(bpy)}2(μ-tdpc)]2+ showed that [{Ru(ttpy)(bpy)}2(μ-tdpc)]3+ is a Class II mixed-valence system with metal−metal coupling of 400 cm−1 assuming a transition dipole moment length of 21 Å. DFT calculations of tdpc2− suggested that the stability of the HOMO results in weak metal−metal coupling via the hole-superexchange mechanism.

Observation of supramolecular π–π dimerization of a dinuclear ruthenium complex by 1H NMR and ESMS

1998 ◽  
pp. 1909-1910 ◽  
Author(s):  
Eléna Ishow ◽  
André Gourdon
Keyword(s):  
1H Nmr ◽  
Ruthenium Complex ◽  
Dinuclear Ruthenium

scholarly journals Membrane Insertion of a Dinuclear Ruthenium Complex and Implications for Antibacterial Activity

2017 ◽  
Vol 112 (3) ◽  
pp. 380a
Author(s):  
Daniel K. Weber ◽  
Marc-Antoine Sani ◽  
Matthew T. Downton ◽  
J. Grant Collins ◽  
Frances Separovic ◽  
...  
Keyword(s):  
Antibacterial Activity ◽  
Ruthenium Complex ◽  
Membrane Insertion ◽  
Dinuclear Ruthenium

scholarly journals Conversion of oxido-bridged dinuclear ruthenium complex to dicationic dinitrosyl ruthenium complex using proton and nitric oxide: Completion of NO reduction cycle

2011 ◽  
Vol 40 (10) ◽  
pp. 2148-2150 ◽  
Author(s):  
Yasuhiro Arikawa ◽  
Naoki Matsumoto ◽  
Taiki Asayama ◽  
Keisuke Umakoshi ◽  
Masayoshi Onishi
Keyword(s):  
Nitric Oxide ◽  
No Reduction ◽  
Ruthenium Complex ◽  
Reduction Cycle ◽  
Dinuclear Ruthenium

Dinuclear ruthenium bipyridine complexes with a bis(iminodioxolene)-meta-phenylene ligand: magnetic coupling and mixed valence character of the semiquinonato species

2005 ◽  
pp. 3868 ◽  
Author(s):  
Fabrizia Fabrizi De Biani ◽  
Andrea Dei ◽  
Claudio Sangregorio ◽  
Lorenzo Sorace
Keyword(s):  
Mixed Valence ◽  
Magnetic Coupling ◽  
Dinuclear Ruthenium

A New Dinuclear Ruthenium Complex as an Efficient Water Oxidation Catalyst

2009 ◽  
Vol 48 (7) ◽  
pp. 2717-2719 ◽  
Author(s):  
Yunhua Xu ◽  
Torbjörn Åkermark ◽  
Viktor Gyollai ◽  
Dapeng Zou ◽  
Lars Eriksson ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Ruthenium Complex ◽  
Oxidation Catalyst ◽  
Dinuclear Ruthenium

A dinuclear ruthenium complex with both terminal and bridging mercapto ligands

1985 ◽  
Vol 105 (3) ◽  
pp. L9-L10 ◽  
Author(s):  
Kohtaro Osakada ◽  
Takakazu Yamamoto ◽  
Akio Yamamoto ◽  
Akio Takenaka ◽  
Yoshio Sasada
Keyword(s):  
Ruthenium Complex ◽  
Dinuclear Ruthenium
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