Calculation of reaction rate constants for hydrogen–deuterium exchange reactions of methane catalysed by acid zeolites

2001 ◽  
pp. 1108-1109 ◽  
Author(s):  
Ann M. Vos ◽  
Robert A. Schoonheydt ◽  
Frank De Proft ◽  
Paul Geerlings
Keyword(s):  
Rate Constants ◽  
Reaction Rate ◽  
Deuterium Exchange ◽  
Hydrogen Deuterium Exchange ◽  
Exchange Reactions ◽  
Reaction Rate Constants ◽  
Acid Zeolites ◽  
Hydrogen Deuterium

Hydrogen-deuterium-exchange reactions of methoxide-methanol clusters

1990 ◽  
Vol 112 (19) ◽  
pp. 6832-6838 ◽  
Author(s):  
S. E. Barlow ◽  
Dang Thuy Thanh ◽  
Veronica M. Bierbaum
Keyword(s):  
Deuterium Exchange ◽  
Hydrogen Deuterium Exchange ◽  
Exchange Reactions ◽  
Hydrogen Deuterium

Hydrogen-deuterium exchange reactions of carbanions with deuterated alcohols in the gas phase

1978 ◽  
Vol 100 (9) ◽  
pp. 2921-2922 ◽  
Author(s):  
C. H. DePuy ◽  
Veronica M. Bierbaum ◽  
Gary K. King ◽  
R. H. Shapiro
Keyword(s):  
Gas Phase ◽  
Deuterium Exchange ◽  
Hydrogen Deuterium Exchange ◽  
Exchange Reactions ◽  
Hydrogen Deuterium

[3,4-D2]Thiophen: synthesis and scrambling on electron impact

1972 ◽  
Vol 25 (6) ◽  
pp. 1221 ◽  
Author(s):  
RM Dawson ◽  
RG Gillis
Keyword(s):  
Electron Beam ◽  
Electron Impact ◽  
Trifluoroacetic Acid ◽  
Deuterium Exchange ◽  
Hydrogen Deuterium Exchange ◽  
Exchange Reactions ◽  
Hydrogen Deuterium

[3,4-D,]Thiophen (1) has been prepared by hydrogen-deuterium exchange reactions using trifluoroacetic acid. [2,5-D2]Thiophen (2) and (1) show an unexplained difference in the amount of scrambling in the formation of the CHS+ ion on electron impact. This difference is maintained when the electron beam and ion draw-out voltages are varied.

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