Lanthanide(iii) complexation by the ligand 1,3,5-triamino-1,3,5-trideoxy-cis-inositol: an unusual thermodynamic behaviour across the rare-earth series

2003 ◽  
pp. 2745-2749 ◽  
Author(s):  
David Chapon ◽  
Jean-Pierre Morel ◽  
Pascale Delangle ◽  
Christelle Gateau ◽  
Jacques Pécaut
2011 ◽  
Vol 17 (18) ◽  
pp. 5033-5044 ◽  
Author(s):  
Masayoshi Nishiura ◽  
Jens Baldamus ◽  
Takanori Shima ◽  
Kyouichi Mori ◽  
Zhaomin Hou

2007 ◽  
Vol 52 (6) ◽  
pp. 2350-2358 ◽  
Author(s):  
D. Gozzi ◽  
M. Iervolino ◽  
A. Latini

2004 ◽  
Vol 137-140 ◽  
pp. 491-494
Author(s):  
C Laubschat ◽  
S.L Molodtsov ◽  
M Finken ◽  
Yu Kucherenko ◽  
G Behr ◽  
...  

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Emily Been ◽  
Wei-Sheng Lee ◽  
Harold Y. Hwang ◽  
Yi Cui ◽  
Jan Zaanen ◽  
...  

1994 ◽  
Vol 47 (2) ◽  
pp. 365 ◽  
Author(s):  
CJ Kepert ◽  
WM Lu ◽  
BW Skelton ◽  
AH White

Detailed examination of the strucures of the title salts, (tpy)LnCl3.xH2O, across the totality of the rare earth series shows a remarkable interplay of structural type and detail. The predominant phase is the previously studied monoclinic Cm array, a ≈ 7.5, b ≈ 16.6, c ≈ 9.8 Ǻ, β = 90.2°, V ≈ 2200 Ǻ3, Z = 2 formula units. For the initial members of the series (La → Nd ), x is 8; for Dy → Er and Lu, x = 7 is accommodated within the same lattice, as are intermediate degrees of hydration for Sm → Gd . A second monoclinic phase, P 21/c, a ≈ 11.6, b ≈ 13.9, c ≈ 13.8 Ǻ, β ≈ 92.3°, V ≈ 2200 Ǻ3, Z = 4 formula units, is found for Yb and Lu (x = 7); the same phase but with β acute (a ≈ 11.3, b ≈ 14.5, c ≈ 13.3 Ǻ, β ≈ 82.2°, V ≈ 2140 Ǻ3, Z = 4 formula units) is found for Tm (and Y) (x = 6). A less hydrated binuclear phase, x=1, has also been observed for Sm , a 10.179(3), b 9.928(4), c 9.748(4) Ǻα 112.61(3), β 109.85(3), γ 94.72(3)°, V 829.3 Ǻ3, Z = 1 dimer.


2005 ◽  
Vol 13 (11) ◽  
pp. 1172-1183 ◽  
Author(s):  
D. Gozzi ◽  
M. Iervolino

Sign in / Sign up

Export Citation Format

Share Document