Pure rotational spectra of PbSe and PbTe: potential function, Born–Oppenheimer breakdown, field shift effect and magnetic shielding

2008 ◽  
Vol 10 (15) ◽  
pp. 2078 ◽  
Author(s):  
Barbara M. Giuliano ◽  
Luca Bizzocchi ◽  
Stephen Cooke ◽  
Deike Banser ◽  
Mareike Hess ◽  
...  
Keyword(s):  
Potential Function ◽  
Breakdown Field ◽  
Magnetic Shielding ◽  
Rotational Spectra ◽  
Field Shift ◽  
Shift Effect

The rotational spectra, potential function, Born-Oppenheimer breakdown, and magnetic shielding of SnSe and SnTe

2007 ◽  
Vol 126 (11) ◽  
pp. 114305 ◽  
Author(s):  
Luca Bizzocchi ◽  
Barbara M. Giuliano ◽  
Mareike Hess ◽  
Jens-Uwe Grabow
Keyword(s):  
Potential Function ◽  
Magnetic Shielding ◽  
Rotational Spectra

Rotational spectra, potential function, Born–Oppenheimer breakdown and magnetic shielding of SiSe and SiTe

2008 ◽  
Vol 251 (1-2) ◽  
pp. 261-267 ◽  
Author(s):  
Barbara M. Giuliano ◽  
Luca Bizzocchi ◽  
Jens-Uwe Grabow
Keyword(s):  
Potential Function ◽  
Magnetic Shielding ◽  
Rotational Spectra

scholarly journals Nuclear field shift effect of lead in ligand exchange reaction using a crown ether

2011 ◽  
Vol 1 (1) ◽  
pp. 387-392 ◽  
Author(s):  
T. Fujii ◽  
F. Moynier ◽  
A. Agranier ◽  
E. Ponzevera ◽  
M. Abe
Keyword(s):  
Crown Ether ◽  
Ab Initio ◽  
Exchange Reaction ◽  
Ligand Exchange ◽  
Isotope Fractionation ◽  
Ligand Exchange Reaction ◽  
Nuclear Field ◽  
Field Shift ◽  
Shift Effect ◽  
Mass Dependent

AbstractLead isotopes were fractionated by the liquid-liquid extraction technique between an aqueous phase and a crown ether. After purification by ion-exchange chemistry, the 207Pb/206Pb and 208Pb/206Pb isotopic ratios were measured by multiple-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). Isotope fractionations > 0.05‰ have been found. The conventional equilibrium mass-dependent isotope effect estimated by an ab initio calculation was smaller than the Pb isotope fractionation experimentally obtained. Conventional mass-dependent isotope fractionation is not a valuable explanation for our results. The nuclear field shift effect, which results from the isotopic change in the nuclear size and shape, was also estimated by an ab initio method combined with a finite nucleus model. The nuclear field shift effect calculated was in agreement with our experimental results. Therefore, this study reports the first nuclear field shift effect of Pb in an equilibrium ligand exchange reaction.

Mass-independent Dunham analysis of the known electronic states of platinum sulfide, PtS, and analysis of the electronic field-shift effect

2019 ◽  
Vol 151 (9) ◽  
pp. 094303 ◽  
Author(s):  
Jack C. Harms ◽  
Leah C. O’Brien ◽  
James J. O’Brien
Keyword(s):  
Electronic States ◽  
Field Shift ◽  
Shift Effect ◽  
Electronic Field

Nuclear Field Shift Effect in Isotope Fractionation of Mercury during Abiotic Reduction in the Absence of Light

2010 ◽  
Vol 114 (12) ◽  
pp. 4238-4245 ◽  
Author(s):  
Wang Zheng ◽  
Holger Hintelmann
Keyword(s):  
Isotope Fractionation ◽  
Nuclear Field ◽  
Field Shift ◽  
Abiotic Reduction ◽  
Shift Effect

scholarly journals The nuclear field shift effect in chemical exchange reactions

2009 ◽  
Vol 267 (3-4) ◽  
pp. 139-156 ◽  
Author(s):  
Toshiyuki Fujii ◽  
Frédéric Moynier ◽  
Francis Albarède
Keyword(s):  
Chemical Exchange ◽  
Exchange Reactions ◽  
Nuclear Field ◽  
Field Shift ◽  
Shift Effect

The rotational spectra, potential function, Born–Oppenheimer breakdown, and hyperfine structure of GeSe and GeTe

2011 ◽  
Vol 135 (8) ◽  
pp. 084303 ◽  
Author(s):  
Barbara M. Giuliano ◽  
Luca Bizzocchi ◽  
Raquel Sanchez ◽  
Pablo Villanueva ◽  
Vanessa Cortijo ◽  
...  
Keyword(s):  
Hyperfine Structure ◽  
Potential Function ◽  
Rotational Spectra

scholarly journals Nuclear field shift effect in isotope fractionation of thallium

2012 ◽  
Vol 296 (1) ◽  
pp. 261-265 ◽  
Author(s):  
Toshiyuki Fujii ◽  
Frédéric Moynier ◽  
Arnaud Agranier ◽  
Emmanuel Ponzevera ◽  
Minori Abe ◽  
...  
Keyword(s):  
Isotope Fractionation ◽  
Nuclear Field ◽  
Field Shift ◽  
Shift Effect

scholarly journals Nuclear field shift effect in the isotope exchange reaction of cadmium using a crown ether

2009 ◽  
Vol 267 (3-4) ◽  
pp. 157-163 ◽  
Author(s):  
Toshiyuki Fujii ◽  
Frédéric Moynier ◽  
Philippe Telouk ◽  
Francis Albarède
Keyword(s):  
Crown Ether ◽  
Exchange Reaction ◽  
Isotope Exchange ◽  
Isotope Exchange Reaction ◽  
Nuclear Field ◽  
Field Shift ◽  
Shift Effect
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