Mononuclear iron complexes relevant to nonheme iron oxygenases. Synthesis, characterizations and reactivity of Fe-Oxo and Fe-Peroxo intermediates

2009 ◽  
pp. 9587 ◽  
Author(s):  
Aurore Thibon ◽  
Jean-François Bartoli ◽  
Sophie Bourcier ◽  
Frédéric Banse
Keyword(s):  
Iron Complexes ◽  
Nonheme Iron ◽  
Mononuclear Iron

scholarly journals A Facially Coordinating Tris-Benzimidazole Ligand for Nonheme Iron Enzyme Models

2020 ◽  
Author(s):  
David Lacy ◽  
Parami Gunasekera ◽  
Preshit Abhyankar ◽  
Samantha N. Macmillan
Keyword(s):  
Structural Models ◽  
Iron Complexes ◽  
Nonheme Iron ◽  
Synthesis And Characterization ◽  
Enzyme Models

This work describes the synthesis and characterization of new ligands and iron complexes for mononuclear nonheme iron oxygenase structural models.

Molecular and Electronic Structures of Mononuclear Iron Complexes Using Strongly Electron-Donating Ligands and their Oxidized Forms

2008 ◽  
Vol 47 (15) ◽  
pp. 6804-6824 ◽  
Author(s):  
Julia B. H. Strautmann ◽  
Serena DeBeer George ◽  
Eberhard Bothe ◽  
Eckhard Bill ◽  
Thomas Weyhermüller ◽  
...  
Keyword(s):  
Electronic Structures ◽  
Iron Complexes ◽  
Mononuclear Iron

Water Oxidation Catalysis with Nonheme Iron Complexes under Acidic and Basic Conditions: Homogeneous or Heterogeneous?

2013 ◽  
Vol 52 (16) ◽  
pp. 9522-9531 ◽  
Author(s):  
Dachao Hong ◽  
Sukanta Mandal ◽  
Yusuke Yamada ◽  
Yong-Min Lee ◽  
Wonwoo Nam ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Iron Complexes ◽  
Nonheme Iron ◽  
Oxidation Catalysis ◽  
Water Oxidation Catalysis

Alkane hydroxylation catalyzed by a series of mononuclear nonheme iron complexes containing 4-nitropyridine ligands

2008 ◽  
Vol 288 (1-2) ◽  
pp. 83-86 ◽  
Author(s):  
Yutaka Hitomi ◽  
Shinya Furukawa ◽  
Masakazu Higuchi ◽  
Tetsuya Shishido ◽  
Tsunehiro Tanaka
Keyword(s):  
Iron Complexes ◽  
Nonheme Iron ◽  
Alkane Hydroxylation

Mononuclear Iron Complexes with Tetraazadentate Ligands as Water Oxidation Catalysts

2016 ◽  
Vol 2016 (20) ◽  
pp. 3262-3268 ◽  
Author(s):  
Gayatri Panchbhai ◽  
Wangkheimayum Marjit Singh ◽  
Biswanath Das ◽  
Reuben T. Jane ◽  
Anders Thapper
Keyword(s):  
Water Oxidation ◽  
Iron Complexes ◽  
Oxidation Catalysts ◽  
Mononuclear Iron

scholarly journals Coordination and conformational isomers in mononuclear iron complexes with pertinence to the [FeFe] hydrogenase active site

2014 ◽  
Vol 43 (11) ◽  
pp. 4537-4549 ◽  
Author(s):  
Andreas Orthaber ◽  
Michael Karnahl ◽  
Stefanie Tschierlei ◽  
Daniel Streich ◽  
Matthias Stein ◽  
...  
Keyword(s):  
Electronic Properties ◽  
Active Site ◽  
Iron Complexes ◽  
Computational Studies ◽  
Mononuclear Iron ◽  
Conformational Isomers ◽  
Ligand Modification ◽  
Fe Complexes ◽  
Ir Spectroscopic

6 Fe complexes of the type [Fe(X-bdt)(PR2NPh2)(CO)] were prepared and the possibility to tune their electronic properties by ligand modification was demonstrated. IR spectroscopic and computational studies suggest that the compounds exist as a mixture of isomers in solution.

Computational analysis of site differences in selective aliphatic C–H hydroxylation by nonheme iron–oxo complexes

2017 ◽  
Vol 19 (21) ◽  
pp. 13924-13930 ◽  
Author(s):  
Jian Wang ◽  
Yuan-yuan Zhao ◽  
Po-Heng Lee
Keyword(s):  
Computational Analysis ◽  
Iron Complexes ◽  
Nonheme Iron ◽  
Oxo Complexes

The CH3CN-solvent influences selective C–H hydroxylation by nonheme iron complexes due to interactions in the H-bonding formation in H-abstraction.

Unraveling the Mechanism of Water Oxidation Catalyzed by Nonheme Iron Complexes

2014 ◽  
Vol 20 (19) ◽  
pp. 5696-5707 ◽  
Author(s):  
Ferran Acuña-Parés ◽  
Zoel Codolà ◽  
Miquel Costas ◽  
Josep M. Luis ◽  
Julio Lloret-Fillol
Keyword(s):  
Water Oxidation ◽  
Iron Complexes ◽  
Nonheme Iron
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