Reversibility of homolytic aromatic substitution: the reaction of p-xylene with phenyl radicals

1974 ◽  
pp. 987 ◽  
Author(s):  
Roberto Henriquez ◽  
Alistair R. Morgan ◽  
Peter Mulholland ◽  
Derek C. Nonhebel ◽  
George G. Smith
Keyword(s):  
Aromatic Substitution ◽  
Phenyl Radicals ◽  
Homolytic Aromatic Substitution

ChemInform Abstract: REVERSIBILITY OF HOMOLYTIC AROMATIC SUBSTITUTION, THE REACTION OF P-XYLENE WITH PHENYL RADICALS

1975 ◽  
Vol 6 (9) ◽  
pp. no-no
Author(s):  
R. HENRIQUEZ ◽  
A. R. MORGAN ◽  
P. MULHOLLAND ◽  
D. C. NONHEBEL ◽  
G. G. SMITH
Keyword(s):  
Aromatic Substitution ◽  
Phenyl Radicals ◽  
Homolytic Aromatic Substitution

Aromatic substitution. XV. The homolytic methylation of pyridine and 3- and 4-picoline

1967 ◽  
Vol 45 (5) ◽  
pp. 509-513 ◽  
Author(s):  
R. A. Abramovitch ◽  
K. Kenaschuk
Keyword(s):  
Free Radical ◽  
Methyl Radicals ◽  
Aromatic Substitution ◽  
Phenyl Radicals

The ratios of isomers formed in the free-radical methylation of pyridine and 3- and 4-picoline have been determined and the results compared with the corresponding phenylations. The results support the concept that methyl radicals are more nucleophilic than phenyl radicals.

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