Iridium-catalyzed regioselective decarboxylative allylation of β-ketoacids: efficient construction of γ,δ-unsaturated ketones

A highly regioselective protocol is reported for the efficient construction of γ,δ-unsaturated ketones from β-ketoacids and allylic alcohols.

ChemInform Abstract: Iridium-Catalyzed Regioselective Decarboxylative Allylation of β-Ketoacids: Efficient Construction of γ,δ-Unsaturated Ketones.

ChemInform ◽

10.1002/chin.201547083 ◽

2015 ◽

Vol 46 (47) ◽

pp. no-no

Author(s):

Shu-Jie Chen ◽

Guo-Ping Lu ◽

Chun Cai

Keyword(s):

Unsaturated Ketones ◽

Efficient Construction ◽

Chemoselective Hydrogen Transfer Reduction of Unsaturated Ketones to Allylic Alcohols with Solid Zr and Hf Catalysts.

ChemInform ◽

10.1002/chin.200315063 ◽

2003 ◽

Vol 34 (15) ◽

Author(s):

Mario De bruyn ◽

Dirk E. De Vos ◽

Pierre A. Jacobs

Keyword(s):

Hydrogen Transfer ◽

Allylic Alcohols ◽

Chemoselective Reduction of Complexα,β-Unsaturated Ketones to Allylic Alcohols over Ir-Metal Particles onβ Zeolites

Angewandte Chemie International Edition ◽

10.1002/anie.200352275 ◽

2003 ◽

Vol 42 (43) ◽

pp. 5333-5336 ◽

Cited By ~ 39

Author(s):

Mario De bruyn ◽

Simona Coman ◽

Roxana Bota ◽

Vasile I. Parvulescu ◽

Dirk E. De Vos ◽

...

Keyword(s):

Metal Particles ◽

Allylic Alcohols ◽

Disproportionation of acyclic ketones to carboxylate ions and ethers: a poisoning reaction on the way to the chemoselective reduction of α,β-unsaturated ketones to allylic alcohols via hydrogen-transfer catalysed by a nonclassical ruthenium(II) trihydride

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39910001336 ◽

1991 ◽

pp. 1336-1337 ◽

Cited By ~ 11

Author(s):

Claudio Bianchini ◽

Erica Farnetti ◽

Piero Frediani ◽

Mauro Graziani ◽

Maurizio Peruzzini ◽

...

Keyword(s):

Hydrogen Transfer ◽

Allylic Alcohols ◽

Unsaturated Ketones ◽

Acyclic Ketones ◽

The Way

SYNTHESIS OF γ,δ-UNSATURATED KETONES BY THE INTRAMOLECULAR DECARBOXYLATIVE ALLYLATION OF ALLYL β-KETO CARBOXYLATES AND ALKENYL ALLYL CARBONATES CATALYZED BY MOLYBDENUM, NICKEL,AND RHODIUM COMPLEXES

Chemistry Letters ◽

10.1246/cl.1984.1721 ◽

1984 ◽

Vol 13 (10) ◽

pp. 1721-1724 ◽

Cited By ~ 26

Author(s):

Jiro Tsuji ◽

Ichiro Minami ◽

Isao Shimizu

Keyword(s):

Rhodium Complexes ◽

Unsaturated Ketones ◽

ChemInform Abstract: Regiospecific Synthesis of β,γ-Unsaturated Ketones from Allylic Alcohols. Claisen Rearrangement of α-Allyloxy Ketone Enol Derivatives.

Chemischer Informationsdienst ◽

10.1002/chin.198648166 ◽

1986 ◽

Vol 17 (48) ◽

Author(s):

J. L. C. KACHINSKY ◽

R. G. SALOMON

Keyword(s):

Claisen Rearrangement ◽

Allylic Alcohols ◽

ChemInform Abstract: Synthesis of α,β-Unsaturated Ketones by Pd-Catalyzed Decarboxylative Allylation of α-Oxocarboxylates.

ChemInform ◽

10.1002/chin.201219075 ◽

2012 ◽

Vol 43 (19) ◽

pp. no-no

Author(s):

Nuria Rodriguez ◽

Filipe Manjolinho ◽

Matthias F. Gruenberg ◽

Lukas J. Goossen

Keyword(s):

Unsaturated Ketones ◽

Compounds with Transition Metal-Carbon pi-Bonds and Compounds of Groups 10-8 (Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru, Os) ◽

γ,δ-Unsaturated Ketones from Decarboxylative Allylation of β-Oxo Esters and Acids

10.1055/sos-sd-001-00150 ◽

2001 ◽

pp. 1

Author(s):

R. W. Friesen

Keyword(s):

Unsaturated Ketones ◽

Palladium-catalyzed arylation of secondary allylic alcohols in the presence of copper(II) triflate and triphenylphosphine: Selective synthesis of β-aryl-α, β-unsaturated ketones

Journal of Molecular Catalysis A Chemical ◽

10.1016/1381-1169(96)00150-1 ◽

1996 ◽

Vol 112 (2) ◽

pp. 211-215 ◽

Cited By ~ 7

Author(s):

Tetsuya Satoh ◽

Masahiro Miura ◽

Masakatsu Nomura

Keyword(s):

Allylic Alcohols ◽

Selective Synthesis ◽

Unsaturated Ketones ◽

Palladium Catalyzed

Regiospecific synthesis of .beta.,.gamma.-unsaturated ketones from allylic alcohols. Claisen rearrangement of .alpha.-allyloxy ketone enol derivatives

The Journal of Organic Chemistry ◽

10.1021/jo00359a004 ◽

1986 ◽

Vol 51 (9) ◽

pp. 1393-1401 ◽

Cited By ~ 32

Author(s):

Joseph L. C. Kachinsky ◽

Robert G. Salomon

Keyword(s):

Claisen Rearrangement ◽

Allylic Alcohols ◽