Chemoselective Reduction of Complexα,β-Unsaturated Ketones to Allylic Alcohols over Ir-Metal Particles onβ Zeolites

Mario De bruyn; Simona Coman; Roxana Bota; Vasile I. Parvulescu; Dirk E. De Vos; Pierre A. Jacobs

doi:10.1002/anie.200352275

Chemoselective Reduction of Complexα,β-Unsaturated Ketones to Allylic Alcohols over Ir-Metal Particles onβ Zeolites

Angewandte Chemie International Edition ◽

10.1002/anie.200352275 ◽

2003 ◽

Vol 42 (43) ◽

pp. 5333-5336 ◽

Cited By ~ 39

Author(s):

Mario De bruyn ◽

Simona Coman ◽

Roxana Bota ◽

Vasile I. Parvulescu ◽

Dirk E. De Vos ◽

...

Keyword(s):

Metal Particles ◽

Allylic Alcohols ◽

Unsaturated Ketones

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Chemoselective Reduction of Complexα,β-Unsaturated Ketones to Allylic Alcohols over Ir-Metal Particles onβ Zeolites

Angewandte Chemie ◽

10.1002/ange.200352275 ◽

2003 ◽

Vol 115 (43) ◽

pp. 5491-5494 ◽

Cited By ~ 18

Author(s):

Mario De bruyn ◽

Simona Coman ◽

Roxana Bota ◽

Vasile I. Parvulescu ◽

Dirk E. De Vos ◽

...

Keyword(s):

Metal Particles ◽

Allylic Alcohols ◽

Unsaturated Ketones

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Iridium-catalyzed regioselective decarboxylative allylation of β-ketoacids: efficient construction of γ,δ-unsaturated ketones

Chemical Communications ◽

10.1039/c5cc03591k ◽

2015 ◽

Vol 51 (57) ◽

pp. 11512-11514 ◽

Cited By ~ 11

Author(s):

Shu-Jie Chen ◽

Guo-Ping Lu ◽

Chun Cai

Keyword(s):

Allylic Alcohols ◽

Unsaturated Ketones ◽

Efficient Construction ◽

Decarboxylative Allylation

A highly regioselective protocol is reported for the efficient construction of γ,δ-unsaturated ketones from β-ketoacids and allylic alcohols.

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Chemoselective Hydrogen Transfer Reduction of Unsaturated Ketones to Allylic Alcohols with Solid Zr and Hf Catalysts.

ChemInform ◽

10.1002/chin.200315063 ◽

2003 ◽

Vol 34 (15) ◽

Author(s):

Mario De bruyn ◽

Dirk E. De Vos ◽

Pierre A. Jacobs

Keyword(s):

Hydrogen Transfer ◽

Allylic Alcohols ◽

Unsaturated Ketones

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Disproportionation of acyclic ketones to carboxylate ions and ethers: a poisoning reaction on the way to the chemoselective reduction of α,β-unsaturated ketones to allylic alcohols via hydrogen-transfer catalysed by a nonclassical ruthenium(II) trihydride

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39910001336 ◽

1991 ◽

pp. 1336-1337 ◽

Cited By ~ 11

Author(s):

Claudio Bianchini ◽

Erica Farnetti ◽

Piero Frediani ◽

Mauro Graziani ◽

Maurizio Peruzzini ◽

...

Keyword(s):

Hydrogen Transfer ◽

Allylic Alcohols ◽

Unsaturated Ketones ◽

Acyclic Ketones ◽

The Way

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ChemInform Abstract: Regiospecific Synthesis of β,γ-Unsaturated Ketones from Allylic Alcohols. Claisen Rearrangement of α-Allyloxy Ketone Enol Derivatives.

Chemischer Informationsdienst ◽

10.1002/chin.198648166 ◽

1986 ◽

Vol 17 (48) ◽

Author(s):

J. L. C. KACHINSKY ◽

R. G. SALOMON

Keyword(s):

Claisen Rearrangement ◽

Allylic Alcohols ◽

Unsaturated Ketones

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Palladium-catalyzed arylation of secondary allylic alcohols in the presence of copper(II) triflate and triphenylphosphine: Selective synthesis of β-aryl-α, β-unsaturated ketones

Journal of Molecular Catalysis A Chemical ◽

10.1016/1381-1169(96)00150-1 ◽

1996 ◽

Vol 112 (2) ◽

pp. 211-215 ◽

Cited By ~ 7

Author(s):

Tetsuya Satoh ◽

Masahiro Miura ◽

Masakatsu Nomura

Keyword(s):

Allylic Alcohols ◽

Selective Synthesis ◽

Unsaturated Ketones ◽

Palladium Catalyzed

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Regiospecific synthesis of .beta.,.gamma.-unsaturated ketones from allylic alcohols. Claisen rearrangement of .alpha.-allyloxy ketone enol derivatives

The Journal of Organic Chemistry ◽

10.1021/jo00359a004 ◽

1986 ◽

Vol 51 (9) ◽

pp. 1393-1401 ◽

Cited By ~ 32

Author(s):

Joseph L. C. Kachinsky ◽

Robert G. Salomon

Keyword(s):

Claisen Rearrangement ◽

Allylic Alcohols ◽

Unsaturated Ketones

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Chemoselective Hydrogen Transfer Reduction of Unsaturated Ketones to Allylic Alcohols with Solid Zr and Hf Catalysts

Advanced Synthesis & Catalysis ◽

10.1002/1615-4169(200212)344:10<1120::aid-adsc1120>3.0.co;2-4 ◽

2002 ◽

Vol 344 (10) ◽

pp. 1120-1125 ◽

Cited By ~ 24

Author(s):

Mario De bruyn ◽

Dirk E. De Vos ◽

Pierre A. Jacobs

Keyword(s):

Hydrogen Transfer ◽

Allylic Alcohols ◽

Unsaturated Ketones

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The Mechanism of Oxidation of Allylic Alcohols to α,β-Unsaturated Ketones by Cytochrome P450†

Chemical Research in Toxicology ◽

10.1021/tx9600053 ◽

1996 ◽

Vol 9 (5) ◽

pp. 871-874 ◽

Cited By ~ 18

Author(s):

Giuseppe Bellucci ◽

Cinzia Chiappe ◽

Laura Pucci ◽

Pier Giovanni Gervasi

Keyword(s):

Cytochrome P450 ◽

Allylic Alcohols ◽

Unsaturated Ketones ◽

Mechanism Of Oxidation

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Synthesis of the New Chiral Aminodiphosphine Ligands (R)- and (S)-(.alpha.-Methylbenzyl)bis(2-(diphenylphosphino)ethyl)amine and Their Use in the Enantioselective Reduction of .alpha.,.beta.-Unsaturated Ketones to Allylic Alcohols by Iridium Catalysis

Organometallics ◽

10.1021/om00003a059 ◽

1995 ◽

Vol 14 (3) ◽

pp. 1489-1502 ◽

Cited By ~ 34

Author(s):

Claudio Bianchini ◽

Erica Farnetti ◽

Lionel Glendenning ◽

Mauro Graziani ◽

Giorgio Nardin ◽

...

Keyword(s):

Allylic Alcohols ◽

Unsaturated Ketones ◽

Iridium Catalysis ◽

Enantioselective Reduction ◽

Alpha Beta ◽

Ethyl Amine

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