SYNTHESIS OF γ,δ-UNSATURATED KETONES BY THE INTRAMOLECULAR DECARBOXYLATIVE ALLYLATION OF ALLYL β-KETO CARBOXYLATES AND ALKENYL ALLYL CARBONATES CATALYZED BY MOLYBDENUM, NICKEL,AND RHODIUM COMPLEXES

In 1998, Hayashi and Miyaura reported the first asymmetric conjugate addition of aryl- and alkenyl-boronic acids to α,β-unsaturated ketones using chiral rhodium complexes as catalysts.

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ChemInform Abstract: Synthesis of α,β-Unsaturated Ketones by Pd-Catalyzed Decarboxylative Allylation of α-Oxocarboxylates.

ChemInform ◽

10.1002/chin.201219075 ◽

2012 ◽

Vol 43 (19) ◽

pp. no-no

Author(s):

Nuria Rodriguez ◽

Filipe Manjolinho ◽

Matthias F. Gruenberg ◽

Lukas J. Goossen

Keyword(s):

Unsaturated Ketones ◽

Decarboxylative Allylation

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γ,δ-Unsaturated Ketones from Decarboxylative Allylation of β-Oxo Esters and Acids

Compounds with Transition Metal-Carbon pi-Bonds and Compounds of Groups 10-8 (Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru, Os) ◽

10.1055/sos-sd-001-00150 ◽

2001 ◽

pp. 1

Author(s):

R. W. Friesen

Keyword(s):

Unsaturated Ketones ◽

Decarboxylative Allylation

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ChemInform Abstract: Iridium-Catalyzed Regioselective Decarboxylative Allylation of β-Ketoacids: Efficient Construction of γ,δ-Unsaturated Ketones.

ChemInform ◽

10.1002/chin.201547083 ◽

2015 ◽

Vol 46 (47) ◽

pp. no-no

Author(s):

Shu-Jie Chen ◽

Guo-Ping Lu ◽

Chun Cai

Keyword(s):

Unsaturated Ketones ◽

Efficient Construction ◽

Decarboxylative Allylation

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Synthesis of α,β-Unsaturated Ketones by Pd-Catalyzed Decarboxylative Allylation of α-Oxocarboxylates

Chemistry - A European Journal ◽

10.1002/chem.201102584 ◽

2011 ◽

Vol 17 (49) ◽

pp. 13688-13691 ◽

Cited By ~ 23

Author(s):

Nuria Rodríguez ◽

Filipe Manjolinho ◽

Matthias F. Grünberg ◽

Lukas J. Gooßen

Keyword(s):

Unsaturated Ketones ◽

Decarboxylative Allylation

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Asymmetric 1,4-addition of alkenylzirconium reagents to $alpha;,$beta;-unsaturated ketones catalyzed by chiral rhodium complexes

Tetrahedron Letters ◽

10.1016/s0040-4039(04)01007-x ◽

2004 ◽

Author(s):

S OI

Keyword(s):

Rhodium Complexes ◽

Unsaturated Ketones ◽

Alpha Beta

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Asymmetric 1,4-addition of alkenylzirconium reagents to α,β-unsaturated ketones catalyzed by chiral rhodium complexes

Tetrahedron Letters ◽

10.1016/j.tetlet.2004.04.171 ◽

2004 ◽

Vol 45 (26) ◽

pp. 5051-5055 ◽

Cited By ~ 56

Author(s):

Shuichi Oi ◽

Takashi Sato ◽

Yoshio Inoue

Keyword(s):

Rhodium Complexes ◽

Unsaturated Ketones

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