Aluminum alkoxide, amide and halide complexes supported by a bulky dipyrromethene ligand: synthesis, characterization, and preliminary ε-caprolactone polymerization activity

2016 ◽  
Vol 45 (35) ◽  
pp. 13787-13797 ◽  
Author(s):  
Christopher G. Gianopoulos ◽  
Nishant Kumar ◽  
Yihong Zhao ◽  
Li Jia ◽  
Kristin Kirschbaum ◽  
...  
Keyword(s):  
Aluminum Alkoxide ◽  
Aluminum Complexes ◽  
Halide Complexes ◽  
Ligand Synthesis

The synthesis, characterization, and ε-caprolactone polymerization activity of aluminum complexes supported by the bulky dipyrromethene (1) ligand are reported.

High Purity Solvent-Coordinated Tin Halide Complexes for Lead Free Perovskite Solar Cells

2017 ◽  
Author(s):  
Jiewei Liu ◽  
Masashi Ozaki ◽  
Yukie Katsuki ◽  
Taketo Handa ◽  
Ryosuke Nishikubo ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Purity ◽  
Perovskite Solar Cells ◽  
Lead Free ◽  
Halide Complexes

A side-on Mn(iii)–peroxo supported by a non-heme pentadentate N3Py2 ligand: synthesis, characterization and reactivity studies

2021 ◽  
Author(s):  
Dattaprasad D. Narulkar ◽  
Azaj Ansari ◽  
Anil Kumar Vardhaman ◽  
Sarvesh S. Harmalkar ◽  
Giribabu Lingamallu ◽  
...  
Keyword(s):  
Nucleophilic Reactivity ◽  
Ligand Synthesis ◽  
Aldehyde Oxidation

A new non-heme Mn(iii)–peroxo (1a) has been generated, characterized and reactivity is in aldehyde deformylation reaction. A nucleophilic reactivity of 1a in aldehyde oxidation is proposed.

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