scholarly journals Ring opening metathesis polymerization of cyclopentene using a ruthenium catalyst confined by a branched polymer architecture

2016 ◽  
Vol 7 (17) ◽  
pp. 2923-2928 ◽  
Author(s):  
Clément Mugemana ◽  
Konstantin V. Bukhryakov ◽  
Olivier Bertrand ◽  
Khanh B. Vu ◽  
Jean-François Gohy ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ruthenium Catalyst ◽  
Star Polymer ◽  
Ring Opening Metathesis Polymerization ◽  
Polymer Architecture ◽  
Branched Polymer ◽  
Metathesis Polymerization ◽  
The Core ◽  
Metathesis Catalyst

A Grubbs-type Ru alkene metathesis catalyst has been covalently anchored in the core of a globular star polymer. The spatially-confined catalyst is capable of efficient ring-opening metathesis polymerization of cyclopentene, a low-strain monomer.

Ring-Opening Metathesis Polymerization in Miniemulsion Using a TEGylated Ruthenium-Based Metathesis Catalyst

2018 ◽  
Vol 51 (22) ◽  
pp. 9088-9096 ◽  
Author(s):  
Chunyang Zhu ◽  
Xiaowei Wu ◽  
Olena Zenkina ◽  
Matthew T. Zamora ◽  
Karen Moffat ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization ◽  
Metathesis Catalyst

Preparation and activity of ruthenium catalyst based on β-cyclodextrin for ring-opening metathesis polymerization

2021 ◽  
Vol 63 ◽  
pp. 152712
Author(s):  
Daichi Yoshida ◽  
Garry Sinawang ◽  
Motofumi Osaki ◽  
Hiroyasu Yamaguchi ◽  
Akira Harada ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ruthenium Catalyst ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization

scholarly journals Living Ring-Opening Metathesis Polymerization of Exo-Norbornenes Bearing Both Cyano and Ester Functionalities by a Well-Defined Ruthenium Catalyst

2007 ◽  
Vol 39 (4) ◽  
pp. 318-329 ◽  
Author(s):  
Yasushi Nishihara ◽  
Yoshiaki Inoue ◽  
Akira T Saito ◽  
Yuushou Nakayama ◽  
Takeshi Shiono ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ruthenium Catalyst ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization

scholarly journals Synthesis of highly stable dual-site immobilized ruthenium olefin metathesis catalyst without ru leaching

2021 ◽  
Vol 2131 (4) ◽  
pp. 042055
Author(s):  
Huanhuan Zhao ◽  
Yanwu Zhang
Keyword(s):  
Block Copolymer ◽  
Olefin Metathesis ◽  
Ring Opening ◽  
Ring Opening Metathesis Polymerization ◽  
Ring Closing Metathesis ◽  
Metathesis Polymerization ◽  
Immobilized Catalyst ◽  
Excellent Activity ◽  
Metathesis Catalyst ◽  
Dual Site

Abstract The tri-block copolymer is used as a carrier to simultaneously immobilize the N-heterocyclic and benzylidene ligands precursor of the Ru-based catalyst to form a dual-site immobilized catalyst. The dual-site immobilized catalyst can catalyze ring-opening metathesis polymerization, ring-closing metathesis and self-metathesis. The dual-site immobilized catalyst shows good heterogeneity in dichloromethane, which simplifies the purification of product and recovery of catalyst. The dual-site immobilized catalyst exhibits excellent activity and recycling performance. The excellent recyclability can be attributed to the capture of ruthenium by the excess ligands precursor on carrier. Importantly, ruthenium residues are not detected in product.

Ring-opening metathesis polymerization of deltacyclene via a ruthenium catalyst

1989 ◽  
Vol 22 (10) ◽  
pp. 4132-4134 ◽  
Author(s):  
Mark Lautens ◽  
Alaa S. Abd-El-Aziz ◽  
Jurgen Reibel
Keyword(s):  
Ring Opening ◽  
Ruthenium Catalyst ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization
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