Three new compounds based on similar molybdenum–vanadium clusters and several types of copper complexes

CrystEngComm ◽  
2018 ◽  
Vol 20 (7) ◽  
pp. 969-977 ◽  
Author(s):  
Li-Na Xiao ◽  
Chun-Xiang Zhao ◽  
Xiao-Ming Shi ◽  
Hao Zhang ◽  
Wen Wu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Copper Complexes ◽  
Inorganic Hybrid ◽  
Hybrid Compounds ◽  
New Compounds

A series of new organic–inorganic hybrid compounds based on Mo–V clusters and several types of transition metal complexes have been synthesized and characterized.

A series of organic–inorganic hybrid compounds formed by [P2W18O62]6−and several types of transition metal complexes

2017 ◽  
Vol 46 (41) ◽  
pp. 14393-14405 ◽  
Author(s):  
Ying Lü ◽  
Li-Na Xiao ◽  
Xiang-Rong Hao ◽  
Xiao-Bing Cui ◽  
Ji-Qing Xu
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Inorganic Hybrid ◽  
Hybrid Compounds

A series of new organic–inorganic hybrid compounds based on [P2W18O62]6−and several types of transition metal complexes have been synthesized and characterized.

Two Novel Organic–Inorganic Hybrid Compounds Constructed from Anderson-type Clusters and Transition-Metal Complexes

2009 ◽  
Vol 20 (3) ◽  
pp. 535-543 ◽  
Author(s):  
Ying Liu ◽  
Shuxia Liu ◽  
Hongmei Ji ◽  
Shiwei Zhang ◽  
Lili Cai ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Inorganic Hybrid ◽  
Hybrid Compounds

3d - 4f Heterometallic Complexes for the Construction of POM-based Inorganic - Organic Hybrid Compounds: from Nanoclusters to One-Dimensional Ladder-Like Chains

2010 ◽  
Vol 63 (9) ◽  
pp. 1389 ◽  
Author(s):  
Dongying Du ◽  
Junsheng Qin ◽  
Shunli Li ◽  
Yaqian Lan ◽  
Xinlong Wang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Transition Metal Complexes ◽  
Lanthanide Complexes ◽  
Copper Complexes ◽  
Heterometallic Complexes ◽  
Magnetic Studies ◽  
One Dimensional ◽  
Organic Hybrid ◽  
Hybrid Compounds ◽  
Polyanion Chain

Three polyoxometalate-based inorganic–organic hybrid compounds, namely nanoclusters [Cu(en)2H2O]3[(α-SiW11O39)Nd(H2O)(η2,μ-1,1)-CH3COO]·3.5H2O (1) and [Cu(en)2H2O]3[(α-SiW11O39)Sm(H2O)(η2,μ-1,1)-CH3COO]·3H2O (2), and 1D H2[Cu(en)2H2O]8[Cu(en)2]3[{(α-SiW11O39)Ce(H2O)(η2,μ-1,1)-CH3COO}4]·22H2O (3) (en = 1,2-ethylenediamine) have been isolated. 1 and 2 are isomorphic and consist of [(α-SiW11O39)Ln(H2O)(η2,μ-1,1)-CH3COO]6– polyanions modified by [Cu(en)2H2O]2+ fragments. In 3, [Cu(en)2H2O]2+ are grafted on [(α-SiW11O39)Ce(H2O)(η2,μ-1,1)-CH3COO]6– polyanions and further connected by [Cu(en)2]2+ groups, representing the first example in polyoxometalate chemistry of a 1D ladder-like polyanion chain consisting of monovacant Keggin-type polyanions, lanthanide complexes and transition metal complexes. In these compounds, copper complexes coordinate to not only terminal O atoms but also bridging O atoms of the polyanions. Magnetic studies of 1 and 3 reveal weak antiferromagnetic interactions exist in them.

Two new compounds of polyoxoanions, transition metal complexes and organic amines

2018 ◽  
Vol 477 ◽  
pp. 292-299 ◽  
Author(s):  
Shu-Yun Shi ◽  
Ling-Yu Chen ◽  
Tong-Hui Zhu ◽  
Jun Zhang ◽  
Xiao-Bing Cui
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Organic Amines ◽  
New Compounds
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