The role of coordinated solvent on Co(ii) ions in tuning the single molecule magnet properties in a {CoII2DyIII2} system

2017 ◽  
Vol 46 (16) ◽  
pp. 5337-5343 ◽  
Author(s):  
Yan Peng ◽  
Valeriu Mereacre ◽  
Christopher E. Anson ◽  
Annie K. Powell
Keyword(s):  
Single Molecule ◽  
Solvent Molecule ◽  
Coordination Geometry ◽  
Single Molecule Magnet ◽  
System P

The anisotropy of a single DyIII can be steered through subtle changes in the coordination geometry of the CoII ions in CoII2DyIII2 butterfly compounds resulting from changing the coordinated solvent molecule on the CoII ion.

Role of the Orbitally Degenerate Mn(III) Ions in the Single-Molecule Magnet Behavior of the Cyanide Cluster {[MnII(tmphen)2]3[MnIII(CN)6]2} (tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline)

2004 ◽  
Vol 126 (51) ◽  
pp. 16860-16867 ◽  
Author(s):  
Andrei V. Palii ◽  
Sergei M. Ostrovsky ◽  
Sophia I. Klokishner ◽  
Boris S. Tsukerblat ◽  
Curtis P. Berlinguette ◽  
...  
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnet

(Invited) The Role of Gd in the Dy2GdN@C80 single Molecule Magnet

2021 ◽  
Vol MA2021-01 (13) ◽  
pp. 630-630
Author(s):  
Thomas Greber
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnet

Systematic studies of hexanuclear {MIII4LnIII2} complexes (M = Fe, Ga; Ln = Er, Ho): structures, magnetic properties and SMM behavior

2017 ◽  
Vol 4 (6) ◽  
pp. 927-934 ◽  
Author(s):  
Sihuai Chen ◽  
Valeriu Mereacre ◽  
George E. Kostakis ◽  
Christopher E. Anson ◽  
Annie K. Powell
Keyword(s):  
Magnetic Properties ◽  
Single Molecule ◽  
Single Molecule Magnet

The first heterometallic GaIII–ErIII single-molecule magnet has been synthesized and the role of GaIII in extracting the FeIII–ErIII and ErIII–ErIII interaction has been assessed.

A Non‐sandwiched Macrocyclic Monolanthanide Single‐Molecule Magnet: The Key Role of Axiality

2011 ◽  
Vol 17 (16) ◽  
pp. 4362-4365 ◽  
Author(s):  
Humphrey L. C. Feltham ◽  
Yanhua Lan ◽  
Frederik Klöwer ◽  
Liviu Ungur ◽  
Liviu F. Chibotaru ◽  
...  
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnet

Sandwich-Type Mixed Tetrapyrrole Rare-Earth Triple-Decker Compounds. Effect of the Coordination Geometry on the Single-Molecule-Magnet Nature

2013 ◽  
Vol 52 (15) ◽  
pp. 8505-8510 ◽  
Author(s):  
Jinglan Kan ◽  
Hailong Wang ◽  
Wei Sun ◽  
Wei Cao ◽  
Jun Tao ◽  
...  
Keyword(s):  
Rare Earth ◽  
Single Molecule ◽  
Coordination Geometry ◽  
Single Molecule Magnet ◽  
Sandwich Type

A Nonsymmetric Dy2 Single-Molecule Magnet with two Relaxation Processes Triggered by External Magnetic Field: Theoretical and Integrated EPR study of the Role of Magnetic-Site Dilution

2022 ◽  
Author(s):  
Nikolia Lalioti ◽  
Vassilis Nastopoulos ◽  
Nikolaos Panayiotou ◽  
Anastasios Tasiopoulos ◽  
Nikolaos Ioannidis ◽  
...  
Keyword(s):  
Magnetic Field ◽  
External Magnetic Field ◽  
Single Molecule ◽  
Good Yield ◽  
Relaxation Processes ◽  
Single Molecule Magnet

The 1:2 reaction between Dy(O2CMe)34H2O and 1-acetyl-2-napthol (LH) in MeOH has provided access to complex [Dy2L6(MeOH)]MeOH (1.MeOH) in good yield. The structures of the isomorphous complexes 1MeOH and its doped...

Back Cover: A Non‐sandwiched Macrocyclic Monolanthanide Single‐Molecule Magnet: The Key Role of Axiality (Chem. Eur. J. 16/2011)

2011 ◽  
Vol 17 (16) ◽  
pp. 4660-4660
Author(s):  
Humphrey L. C. Feltham ◽  
Yanhua Lan ◽  
Frederik Klöwer ◽  
Liviu Ungur ◽  
Liviu F. Chibotaru ◽  
...  
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnet ◽  
Back Cover

Carboxylate-Bridged Dinuclear Dy2 Single-Molecule Magnets: Synthesis, Structure, and Magnetic Studies

2013 ◽  
Vol 66 (1) ◽  
pp. 98 ◽  
Author(s):  
Yu-mei Song ◽  
Feng Luo ◽  
Yan Zhu ◽  
Xiao-zhao Tian ◽  
Gong-ming Sun
Keyword(s):  
Magnetic Properties ◽  
Single Molecule ◽  
Coordination Geometry ◽  
Magnetic Studies ◽  
Single Molecule Magnets ◽  
Chlorobenzoic Acid ◽  
Ferromagnetic Interaction ◽  
Single Molecule Magnet ◽  
The Difference

In this work, the synthesis, structure, and magnetic studies of three dinuclear Dy2 compounds, namely Dy2(bpy)2(L)6 (1), Dy2(phen)2(L)6 (2), Dy2(μ-H2O)2(bpy)2(L)6 (3) are reported in detail, where HL, phen, and bpy are 4-chlorobenzoic acid, 1,10-phenanthroline, and 2,2′-bipyridine. Magnetic studies reveal the intramolecular ferromagnetic interaction and single-molecule magnetic properties of these compounds. The fine-tuned single-molecule magnet properties of compounds 1–3, mainly due to the difference of the coordination geometry of DyIII ions, are highlighted.

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