Controlled ring-opening polymerisation of cyclic phosphates, phosphonates and phosphoramidates catalysed by heteroleptic BHT-alkoxy magnesium complexes

2017 ◽  
Vol 8 (44) ◽  
pp. 6806-6816 ◽  
Author(s):  
I. E. Nifant'ev ◽  
A. V. Shlyakhtin ◽  
V. V. Bagrov ◽  
P. D. Komarov ◽  
M. A. Kosarev ◽  
...  
Keyword(s):  
Ring Opening ◽  
Magnesium Complexes ◽  
Cyclic Phosphates

BHT-Mg-alkoxides are readily available and effective ROP catalysts for cyclic ethylene phosphate monomers and outperform conventional organocatalysts in versatility.

Magnesium Complexes Containing η1- and η3-Pyrrolyl or Ketiminato Ligands: Synthesis, Structural Investigation and ϵ-Caprolactone Ring-Opening Polymerisation

2011 ◽  
Vol 2011 (36) ◽  
pp. 5530-5537 ◽  
Author(s):  
Li-Feng Hsueh ◽  
Nien-Tsu Chuang ◽  
Cheng-Yuan Lee ◽  
Amitabha Datta ◽  
Jui-Hsien Huang ◽  
...  
Keyword(s):  
Ring Opening ◽  
Structural Investigation ◽  
Magnesium Complexes

Diastereoselective synthesis of chiral aminophenolate magnesium complexes and their application in the stereoselective polymerization of rac-lactide and rac-β-butyrolactone

2016 ◽  
Vol 45 (27) ◽  
pp. 10942-10953 ◽  
Author(s):  
Haobing Wang ◽  
Jianshuang Guo ◽  
Yang Yang ◽  
Haiyan Ma
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Diastereoselective Synthesis ◽  
Magnesium Complexes

A series of magnesium silylamido complexes supported by chiral aminophenolate ligands were synthesized, and their catalytic behaviors toward the ring-opening polymerization of rac-lactide (LA) and rac-β-butyrolactone (BBL) were explored.

Magnesium complexes containing bis-amido-oxazolinate ligands as efficient catalysts for ring opening polymerisation of l-lactide

2009 ◽  
pp. 9068 ◽  
Author(s):  
Ming-Tsz Chen ◽  
Ping-Jung Chang ◽  
Chi-An Huang ◽  
Kuo-Fu Peng ◽  
Chi-Tien Chen
Keyword(s):  
Ring Opening ◽  
Magnesium Complexes

(Benz)Imidazolin-2-iminato Aluminum, Zinc, and Magnesium Complexes and Their Applications in Ring Opening Polymerization of ε-Caprolactone

2019 ◽  
Vol 58 (19) ◽  
pp. 13426-13439 ◽  
Author(s):  
Heng Liu ◽  
Maxim Khononov ◽  
Natalia Fridman ◽  
Matthias Tamm ◽  
Moris S. Eisen
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Magnesium Complexes

Discrete Cationic Zinc and Magnesium Complexes for Dual Organic/Organometallic-Catalyzed Ring-Opening Polymerization of Trimethylene Carbonate

2012 ◽  
Vol 18 (30) ◽  
pp. 9360-9370 ◽  
Author(s):  
Pierre Brignou ◽  
Sophie M. Guillaume ◽  
Thierry Roisnel ◽  
Didier Bourissou ◽  
Jean-François Carpentier
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Trimethylene Carbonate ◽  
Magnesium Complexes

Ring-opening polymerization of lactides catalyzed by magnesium complexes coordinated with NNO-tridentate pyrazolonate ligands

2012 ◽  
Vol 51 (3) ◽  
pp. 696-707 ◽  
Author(s):  
Hui-Ju Chuang ◽  
Hsiao-Li Chen ◽  
Jian-Li Ye ◽  
Zn-Yun Chen ◽  
Pei-Ling Huang ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Magnesium Complexes
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