scholarly journals A polysalen based on polyacylamide stabilized palladium nanoparticle catalyst for efficient carbonylative Sonogashira reaction in aqueous media

RSC Advances ◽  
2017 ◽  
Vol 7 (51) ◽  
pp. 31850-31857 ◽  
Author(s):  
Yan Wang ◽  
Xiaolong Yang ◽  
Jianqiang Yu
Keyword(s):  
Aqueous Media ◽  
Pd Nanoparticles ◽  
Sonogashira Reaction ◽  
Sonogashira Coupling ◽  
Terminal Alkynes ◽  
Palladium Nanoparticle ◽  
Aryl Iodides ◽  
Nanoparticle Catalyst

Pd nanoparticles immobilized on polysalen based on polyacylamide was synthesized and used for carbonylative Sonogashira coupling of aryl iodides with terminal alkynes to produce α,β-alkynyl ketones in aqueous media.

CuI/PPh3-catalyzed Sonogashira coupling reaction of aryl iodides with terminal alkynes in water in the absence of palladium

2009 ◽  
Vol 23 (2) ◽  
pp. 75-77 ◽  
Author(s):  
Jin Tao Guan ◽  
Guang-Ao Yu ◽  
Lei Chen ◽  
Tan Qing Weng ◽  
Jing Jing Yuan ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Sonogashira Coupling ◽  
Terminal Alkynes ◽  
Aryl Iodides ◽  
Sonogashira Coupling Reaction

A convenient synthesis of CF3-containing alkynyl imines by a copper-free Sonogashira coupling of imidoyl chlorides with terminal alkynes

2008 ◽  
Vol 2008 (11) ◽  
pp. 637-639 ◽  
Author(s):  
Muwang Chen ◽  
Qiaochu Zhang ◽  
Xingguo Zhang ◽  
Ping Zhong ◽  
Maolin Hu
Keyword(s):  
Sonogashira Reaction ◽  
Sonogashira Coupling ◽  
Terminal Alkynes ◽  
Convenient Synthesis ◽  
Imidoyl Chlorides

A series of N-aryltrifluoroacetimidoyl chlorides and 1-alkynes were converted into α-imino alkynes by a Sonogashira reaction using Pd(PPh3)4/DABCO as the catalyst. The reaction proceeded smoothly to give the coupled products in good to excellent yields.

ChemInform Abstract: FeCl3/PPh3-Catalyzed Sonogashira Coupling Reaction of Aryl Iodides with Terminal Alkynes.

ChemInform ◽  
2010 ◽  
Vol 41 (34) ◽  
pp. no-no
Author(s):  
Dinesh N. Sawant ◽  
Pawan J. Tambade ◽  
Yogesh S. Wagh ◽  
Bhalchandra M. Bhanage
Keyword(s):  
Coupling Reaction ◽  
Sonogashira Coupling ◽  
Terminal Alkynes ◽  
Aryl Iodides ◽  
Sonogashira Coupling Reaction

ChemInform Abstract: 2,2′-Diamino-6,6′-dimethylbiphenyl as an Efficient Ligand in the CuI-Catalyzed Sonogashira Reaction of Aryl Iodides and Bromides with Terminal Alkynes.

ChemInform ◽  
2011 ◽  
Vol 42 (36) ◽  
pp. no-no
Author(s):  
Bin-Bin Wang ◽  
Yue-Mei Ye ◽  
Jun-Jun Chen ◽  
Xia-Xia Zhou ◽  
Jian-Mei Lu ◽  
...  
Keyword(s):  
Sonogashira Reaction ◽  
Terminal Alkynes ◽  
Aryl Iodides

scholarly journals The effects of amines on oxidative homo-coupling of terminal alkynes promoted by copper salts

2005 ◽  
Vol 2005 (2) ◽  
pp. 112-115 ◽  
Author(s):  
Lei Wang ◽  
Jincan Yan ◽  
Pinhua Li ◽  
Min Wang ◽  
Caina Su
Keyword(s):  
Reaction Medium ◽  
Cross Coupling ◽  
Catalytic Amount ◽  
Sonogashira Reaction ◽  
Coupling Reactions ◽  
Sonogashira Coupling ◽  
Terminal Alkynes ◽  
Copper Salts ◽  
Terminal Acetylenes ◽  
Glaser Coupling

The effects of all kinds of amines on homo-couplings (Glaser reactions) of terminal alkynes promoted by copper salts and the Sonogashira coupling reactions were studied systematically. Diethylamine (2° amine) can serve as an excellent solvent, base and coordination ligand in the oxidative homo-coupling of terminal alkynes and several modified Glaser coupling procedures have been developed which are based on a catalytic amount of cuprous salts (CuI, CuBr or CuCl) with diethylamine systems. Homo-coupling of terminal acetylenes in the Sonogashira reaction could be inhibited by using triethylamine (3° amine) as reaction medium, and the cross-coupling products were formed as the exclusive products.

MnCl 2 ‐Mediated Carbonylative Sonogashira Coupling of Aryl Iodides and Aromatic Terminal Alkynes by Using CO

2019 ◽  
Vol 4 (39) ◽  
pp. 11553-11556
Author(s):  
Parvathi K. Lakshmi ◽  
Sarma V. Markandeya ◽  
Chidara Sridhar ◽  
Raghu Babu K
Keyword(s):  
Sonogashira Coupling ◽  
Terminal Alkynes ◽  
Aryl Iodides
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