Gradient helical copolymers: synthesis, chiroptical properties, thermotropic liquid crystallinity, and self-assembly in selective organic solvents

A series of novel gradient copolymers R-(−)-poly(StN-grad-C8) were synthesized through atom transfer radical copolymerization of an achiral styrenic monomer, N,N-dimethyl-4-ethenylbenzamide (M-StN), and a chiral bulky vinylterphenyl monomer, (−)-2,5-bis{4′-[(R)-sec-octyloxycarbonyl]phenyl}styrene (R-(−)-M-C8).

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Tailoring the morphology of branched poly(N-isopropylacrylamide) via self-condensing atom-transfer radical copolymerization and its unique self-assembly behavior in alcohol

Soft Matter ◽

10.1039/c1sm05459g ◽

2011 ◽

Vol 7 (16) ◽

pp. 7526 ◽

Cited By ~ 14

Author(s):

Shengtong Sun ◽

Peiyi Wu

Keyword(s):

Self Assembly ◽

Radical Copolymerization ◽

Atom Transfer ◽

Assembly Behavior

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Gradient copolymers by atom transfer radical copolymerization

Journal of Physical Organic Chemistry ◽

10.1002/1099-1395(200012)13:12<775::aid-poc314>3.0.co;2-d ◽

2000 ◽

Vol 13 (12) ◽

pp. 775-786 ◽

Cited By ~ 273

Author(s):

Krzysztof Matyjaszewski ◽

Michael J. Ziegler ◽

Stephen V. Arehart ◽

Dorota Greszta ◽

Tadeusz Pakula

Keyword(s):

Radical Copolymerization ◽

Atom Transfer ◽

Gradient Copolymers

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Atom Transfer Radical Copolymerization of Acrylamide Under Microwave Irradiation

ACTA AGRONOMICA SINICA ◽

10.3724/sp.j.1095.2013.20243 ◽

2013 ◽

Vol 30 (4) ◽

pp. 398

Author(s):

Wei DING ◽

Ling WANG ◽

Tao YU ◽

Guangmiao QU ◽

Xiang GAO ◽

...

Keyword(s):

Microwave Irradiation ◽

Radical Copolymerization ◽

Atom Transfer

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Development of Branching in Atom Transfer Radical Copolymerization of Styrene with Triethylene Glycol Dimethacrylate

Macromolecules ◽

10.1021/ma900459g ◽

2009 ◽

Vol 42 (16) ◽

pp. 5976-5982 ◽

Cited By ~ 41

Author(s):

Hong-Jun Yang ◽

Bi-Biao Jiang ◽

Wen-Yan Huang ◽

Dong-Liang Zhang ◽

Li-Zhi Kong ◽

...

Keyword(s):

Triethylene Glycol ◽

Radical Copolymerization ◽

Atom Transfer ◽

Glycol Dimethacrylate ◽

Triethylene Glycol Dimethacrylate

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Large Scale Supramolecular Self-Assembly of Graft-Copolymers Prepared by Rapid Evaporation of Organic Solvents

Chemistry Letters ◽

10.1246/cl.1999.1221 ◽

1999 ◽

Vol 28 (11) ◽

pp. 1221-1222 ◽

Cited By ~ 3

Author(s):

Akio Kishida ◽

Fusako Seto ◽

Ken-ichiro Hiwatari ◽

Takeshi Serizawa ◽

Youichiro Muraoka ◽

...

Keyword(s):

Organic Solvents ◽

Self Assembly ◽

Large Scale ◽

Graft Copolymers

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Self-assembly of bilayers from double-chain fluorocarbon amphiphiles in aprotic organic solvents: thermodynamic origin and generalization of the bilayer assembly

Journal of the American Chemical Society ◽

10.1021/ja00092a008 ◽

1994 ◽

Vol 116 (13) ◽

pp. 5579-5591 ◽

Cited By ~ 73

Author(s):

Yuichi Ishikawa ◽

Hiroaki Kuwahara ◽

Toyoki Kunitake

Keyword(s):

Organic Solvents ◽

Self Assembly ◽

Double Chain ◽

Bilayer Assembly

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Optimization of Atom Transfer Radical Copolymerization of Allyl Butyl Ether with Acrylonitrile

Polymer Journal ◽

10.1295/polymj.pj2006160 ◽

2007 ◽

Vol 39 (6) ◽

pp. 558-567

Author(s):

A S Brar ◽

Tripta Saini

Keyword(s):

Radical Copolymerization ◽

Atom Transfer ◽

Butyl Ether

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Highly Branched Polymethacrylates Prepared Efficiently: Brancher-Directed Topology and Application Performance

Polymer Chemistry ◽

10.1039/d1py01273h ◽

2021 ◽

Author(s):

Yang Ma ◽

Hong-Mei Yang ◽

Zhi-Hao Chen ◽

Ya-Ning Li ◽

Jun-Fang Li ◽

...

Keyword(s):

Radical Copolymerization ◽

Branched Polymers ◽

Atom Transfer ◽

Application Performance ◽

Directed Topology

Highly branched polymers are very promising and suitable for a variety of applications. Herein, a series of oil-soluble and branched polymethacrylates are synthesized efficiently via atom transfer radical copolymerization of...

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