Rhodium-catalyzed asymmetric addition of arylboronic acids to 2H-chromenes leading to 3-arylchromane derivatives

2019 ◽  
Vol 55 (79) ◽  
pp. 11876-11879 ◽  
Author(s):  
Moeko Umeda ◽  
Kana Sakamoto ◽  
Tomotaka Nagai ◽  
Midori Nagamoto ◽  
Yusuke Ebe ◽  
...  
Keyword(s):  
Asymmetric Addition ◽  
Arylboronic Acids ◽  
Enantioselective Addition

The Rh-catalyzed enantioselective addition of arylboronic acids to 2H-chromenes proceeded to give 3-arylchromanes with high enantioselectivity.

Synthesis of Solution-Phase Phosphoramidite and Phosphite Ligand Libraries and Their In Situ Screening in the Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids

2007 ◽  
Vol 9 (3) ◽  
pp. 407-414 ◽  
Author(s):  
Richard B. C. Jagt ◽  
Patrick Y. Toullec ◽  
Ebe P. Schudde ◽  
Johannes G. de Vries ◽  
Ben L. Feringa ◽  
...  
Keyword(s):  
Solution Phase ◽  
Asymmetric Addition ◽  
Arylboronic Acids

ChemInform Abstract: Synthesis of Aryl(ferrocenyl)methanols via an Enantioselective Addition of Arylboronic Acids.

ChemInform ◽  
2011 ◽  
Vol 42 (39) ◽  
pp. no-no
Author(s):  
Pavol Tisovsky ◽  
Maria Meciarova ◽  
Radovan Sebesta
Keyword(s):  
Arylboronic Acids ◽  
Enantioselective Addition

Synthesis of a Class of Chiral-Bridged Phosphoramidite Ligands and Their Applications in the First Iridium-Catalyzed Asymmetric Addition of Arylboronic Acids to Isatins

2015 ◽  
Vol 80 (14) ◽  
pp. 6968-6975 ◽  
Author(s):  
Yue Zhuang ◽  
Yuwei He ◽  
Zihong Zhou ◽  
Wang Xia ◽  
Chuyu Cheng ◽  
...  
Keyword(s):  
Asymmetric Addition ◽  
Arylboronic Acids

Ni(II)/tBu-SMI-PHOX catalyzed enantioselective addition of arylboronic acids to cyclic N-sulfonyl aldimines

Tetrahedron ◽  
2020 ◽  
Vol 76 (21) ◽  
pp. 131201
Author(s):  
Rui Sun ◽  
Zhongxuan Qiu ◽  
Guorui Cao ◽  
Dawei Teng
Keyword(s):  
Arylboronic Acids ◽  
Enantioselective Addition

Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to Glyoxylates: Access to Optically Active Substituted Mandelic Acid Esters

Synlett ◽  
2019 ◽  
Vol 30 (14) ◽  
pp. 1693-1697
Author(s):  
Diao Chen ◽  
Jian-Guo Liu ◽  
Xu Zhang ◽  
Ming-Hua Xu
Keyword(s):  
Catalytic System ◽  
Mandelic Acid ◽  
Optically Active ◽  
Antiplatelet Drug ◽  
Reaction Conditions ◽  
Formal Synthesis ◽  
Arylboronic Acids ◽  
Synthetic Utility ◽  
Enantioselective Addition ◽  
Acid Esters

A rhodium-catalyzed enantioselective addition of glyoxylates to arylboronic acids promoted by a simple chiral sulfinamide-based olefin ligand under mild reaction conditions is described. The reaction provides access to a variety of optically active substituted mandelic acid esters in good yields with up to 83% ee. The catalytic system is also applicable to pyruvate addition. The synthetic utility of this method is highlighted by a formal synthesis of the antiplatelet drug clopidogrel.

Chiral Bis-Sulfoxide/Rhodium(I) Catalyzed Asymmetric Addition of Arylboronic Acids

Synfacts ◽  
2008 ◽  
Vol 2008 (05) ◽  
pp. 0489-0489
Keyword(s):  
Asymmetric Addition ◽  
Arylboronic Acids

Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to β-Nitroolefins: Formal Synthesis of (S)-SKF 38393

2013 ◽  
Vol 15 (22) ◽  
pp. 5730-5733 ◽  
Author(s):  
Kung-Chih Huang ◽  
Balraj Gopula ◽  
Ting-Shen Kuo ◽  
Chien-Wei Chiang ◽  
Ping-Yu Wu ◽  
...  
Keyword(s):  
Skf 38393 ◽  
Asymmetric Addition ◽  
Formal Synthesis ◽  
Arylboronic Acids

ChemInform Abstract: An N-Linked Bidentate Phosphoramidite Ligand (N-Me-BIPAM) for Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to N-Sulfonylarylaldimines.

ChemInform ◽  
2009 ◽  
Vol 40 (24) ◽  
Author(s):  
Kazunori Kurihara ◽  
Yasunori Yamamoto ◽  
Norio Miyaura
Keyword(s):  
Asymmetric Addition ◽  
Arylboronic Acids
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