arylboronic acids
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Synlett ◽  
2022 ◽  
Sebastien Redon ◽  
Vincent Remusat ◽  
Patrice Vanelle

A new method of deborylative selanylation using arylboronic acids and arylseleninic acids gave diaryl selenoethers and diarylselenoxide. The present approach requires only equimolar arylseleninic acid and led selectively to selenoethers or selenoxides depending on the solvent. The method is metal-free, base- or oxidant-free, efficient, and environmentally friendly.

Cece Wang ◽  
Lu Zhou ◽  
Jian Qiu ◽  
Kai Yang ◽  
Qiuling Song

Herein we present a diastereoselective addition of arylboronic acids to α-keto N-tert-butanesulfinyl aldimines catalyzed by Rh(I) catalyst. This reaction provides a practical method to deliver valuable chiral α-amino ketones with...

2022 ◽  
Yuzhou Wang ◽  
Yu Yu ◽  
Rongrong Xie ◽  
Ya-Nan Tian ◽  
Lingyu Huang ◽  

Cu/Fe-mediated arylation of pyridines with arylboronic acids, featuring low-cost catalytic system and easy operation, is disclosed. A series of length-controllable linear (the number of aryls ranges from 2 to 6)...

Jack G. Haggett ◽  
Gun Su Han ◽  
Angela R. Moser ◽  
Julian V.A. Golzwarden ◽  
Shubham Vyas ◽  

Reactive oxygen species (ROS) such as H2O2 and peroxynitrite (ONOO-) oxidize arylboronic acids to their corresponding phenols. When used in molecular imaging probes and in ROS-responsive molecules, however, simple arylboronic...

Cong Lin ◽  
Sai Chen ◽  
Yihua Wang ◽  
Fei Gao ◽  
Liang Shen

The Ni(II)-catalyzed intermolecular arylation of unactivated alkenes with arylboronic acids has been disclosed for the first time. This alkene arylation exhibits excellent E/Z selectivity and regioselectivity (γ-selectivity) to provide the...

2021 ◽  
Vol 12 (3) ◽  
pp. 563-572
Said Dagdag ◽  
Mounir Belbahloul ◽  
Maria Kopp ◽  
Abdellah Anouar ◽  
Moustafa Chhiba ◽  

Suzuki cross coupling reaction is one of the most famous organic reactions of the 20th century’s chemistry. It is deemed of as one of the most famous reaction in the field of chemistry. It is a very effective method for making carbon–carbon bonds. It has been extensively utilized in the synthesis of many carbon molecules including the most complex ones.Syntheses of 2-diethylamino-4H-7-(Het) aryl pyrido [1,2-a] [1,3,5] triazin-4-ones are currently under investigation in order to obtain great potentialities in medicinal chemistry of compounds class. The methodology we propose herein is able to produce numerous 2-diethylamino-4H-7-(Het)arylpyrido[1,2-a][1,3,5]triazin-4-one and derivatives that were synthesized, purified and characterized by 1HNMR, 13CNMR, MS techniques. Furthermore, it allows sequential introduction of various substituents into a 2-alkylylamino-4H-7-(Het)arylpyrido[1,2-a][1,3,5]triazin-4-ones ring using a one-pot procedure. The biological evaluation as well as the physico-chemical characterisation of various products are currently under way and will be described elsewhere.

2021 ◽  
Lei Xu ◽  
Fu-Yue Liu ◽  
Qi Zhang ◽  
Wei-Jun Chang ◽  
Zhong-Lin Liu ◽  

ChemSusChem ◽  
2021 ◽  
Dan Wang ◽  
Zhaohua Wan ◽  
Heng Zhang ◽  
Hesham Alhumade ◽  
Hong Yi ◽  

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