Solvent- and anion-dependent rearrangement of fluorinated carbene ligands provides access to fluorinated alkenes

Lewis M. Hall; Lucy M. Milner; Sam J. Hart; Adrian C. Whitwood; Jason M. Lynam; John M. Slattery

doi:10.1039/c9dt04307a

Solvent- and anion-dependent rearrangement of fluorinated carbene ligands provides access to fluorinated alkenes

Dalton Transactions ◽

10.1039/c9dt04307a ◽

2019 ◽

Vol 48 (47) ◽

pp. 17655-17659

Author(s):

Lewis M. Hall ◽

Lucy M. Milner ◽

Sam J. Hart ◽

Adrian C. Whitwood ◽

Jason M. Lynam ◽

...

Keyword(s):

Electrophilic Addition ◽

Carbene Ligands ◽

Vinylidene Complex

The construction of fluorocarbene ligands using sequential nucleophilic and electrophilic addition to a ruthenium vinylidene complex is described. These undergo solvent- and anion-dependent rearrangement to liberate free fluorinated alkenes.

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ChemInform Abstract: Facile Synthesis of N-Substituted Amides from Alkenes and Amides by a Broensted Acid Mediated Electrophilic Addition Reaction.

ChemInform ◽

10.1002/chin.201448053 ◽

2014 ◽

Vol 45 (48) ◽

pp. no-no

Author(s):

Karin Mihara ◽

Iku Okada ◽

Kazuhiro Chiba ◽

Yoshikazu Kitano

Keyword(s):

Addition Reaction ◽

Electrophilic Addition ◽

Facile Synthesis ◽

Electrophilic Addition Reaction

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Complexes LNi(Cp)X with alkylamino-substituted N-heterocyclic carbene ligands (L) and their catalytic activity in the Suzuki—Miyaura reaction

Russian Chemical Bulletin ◽

10.1007/s11172-021-3212-5 ◽

2021 ◽

Vol 70 (7) ◽

pp. 1281-1289

Author(s):

V. V. Chesnokov ◽

M. A. Shevchenko ◽

S. B. Soliev ◽

V. A. Tafeenko ◽

V. M. Chernyshev

Keyword(s):

Catalytic Activity ◽

Carbene Ligands

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ChemInform Abstract: ELECTROPHILIC ADDITION REACTIONS IN TERPENOID SYNTHESIS. VI. (.+-.)-CHRYSANTHEMIC ACID AND ANALOGS THEREOF

Chemischer Informationsdienst ◽

10.1002/chin.197812151 ◽

1978 ◽

Vol 9 (12) ◽

Author(s):

C. F. GARBERS ◽

M. S. BEUKES ◽

C. EHLERS ◽

M. J. MCKENZIE

Keyword(s):

Electrophilic Addition ◽

Addition Reactions

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ChemInform Abstract: Practical New Strategies for Immobilising Ruthenium Alkylidene Complexes. Part 1. Immobilisation via Phosphane, Alkylidene and N-Heterocyclic Carbene Ligands

ChemInform ◽

10.1002/chin.200936223 ◽

2009 ◽

Vol 40 (36) ◽

Author(s):

Ileana Dragutan ◽

Valerian Dragutan

Keyword(s):

Carbene Ligands ◽

New Strategies ◽

Alkylidene Complexes

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Cleavage of acyclic diaminocarbene ligands at an iridium(iii) center. Recognition of a new reactivity mode for carbene ligands

Dalton Transactions ◽

10.1039/c9dt01138b ◽

2019 ◽

Vol 48 (22) ◽

pp. 7571-7582 ◽

Cited By ~ 4

Author(s):

Mikhail A. Kinzhalov ◽

Anzhelika A. Eremina ◽

Andrey S. Smirnov ◽

Vitalii V. Suslonov ◽

Vadim Yu. Kukushkin ◽

...

Keyword(s):

Carbene Ligands ◽

Acyclic Diaminocarbene

A new reactivity mode for acyclic diaminocarbene ligands, viz. competitive cleavage of either C–NH2 or C–NHR bonds in the aminocarbene fragment, is recognized.

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