Slow magnetic relaxation in O–Se–O bridged manganese(iii) Schiff base complexes
Keyword(s):
Two new chain complexes consisting of a Mn(salen) building block bridged by O–Se–O units, [Mn2(salen)2(L)](ClO4) (1) and {[Mn(salen)]2(L)2}·Y (2) (salen = N,N′-bis(salicylidene)-ethylenediamine, L = 3,4,5-trifluorobenzeneseleninic acid, Y = salicylaldehyde) have been synthesized and characterized structurally and magnetically.
Keyword(s):
Keyword(s):
Keyword(s):