Enantioconvergent alkylation of ketones with racemic secondary alcohols via hydrogen borrowing catalysis

An enantioconvergent hydrogen borrowing strategy enables the catalytic asymmetric alkylation of ketone enolates with unactivated, racemic secondary alcohols.

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Catalytic, asymmetric alkylation of imines

Tetrahedron ◽

10.1016/j.tet.2007.06.043 ◽

2007 ◽

Vol 63 (39) ◽

pp. 9581-9597 ◽

Cited By ~ 67

Author(s):

Dana Ferraris∗

Keyword(s):

Asymmetric Alkylation ◽

Catalytic Asymmetric

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ChemInform Abstract: Catalytic Asymmetric Acylation of Racemic Secondary Alcohols with Benzoyl Chloride in the Presence of a Chiral Diamine.

ChemInform ◽

10.1002/chin.199931036 ◽

2010 ◽

Vol 30 (31) ◽

pp. no-no

Author(s):

Tomohumi Sano ◽

Keisuke Imai ◽

Kousaburo Ohashi ◽

Takeshi Oriyama

Keyword(s):

Benzoyl Chloride ◽

Secondary Alcohols ◽

Chiral Diamine ◽

Catalytic Asymmetric

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Catalytic Asymmetric Alkylation of Acylsilanes

Angewandte Chemie ◽

10.1002/ange.201409815 ◽

2014 ◽

Vol 127 (10) ◽

pp. 3081-3085 ◽

Cited By ~ 18

Author(s):

Jiawei Rong ◽

Rik Oost ◽

Alaric Desmarchelier ◽

Adriaan J. Minnaard ◽

Syuzanna R. Harutyunyan

Keyword(s):

Asymmetric Alkylation ◽

Catalytic Asymmetric

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Highly Enantioselective Construction of Quaternary Stereocenters onβ-Keto Esters by Phase-Transfer Catalytic Asymmetric Alkylation and Michael Reaction

Angewandte Chemie ◽

10.1002/ange.200390598 ◽

2003 ◽

Vol 115 (34) ◽

pp. 4111-4111 ◽

Cited By ~ 2

Author(s):

Takashi Ooi ◽

Takashi Miki ◽

Mika Taniguchi ◽

Misato Shiraishi ◽

Mifune Takeuchi ◽

...

Keyword(s):

Michael Reaction ◽

Phase Transfer ◽

Asymmetric Alkylation ◽

Keto Esters ◽

Catalytic Asymmetric ◽

Quaternary Stereocenters

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Innentitelbild: Construction of Quaternary Carbon Center by Catalytic Asymmetric Alkylation of 3‐Arylpiperidin‐2‐ones Under Phase‐Transfer Conditions (Angew. Chem. 6/2020)

Angewandte Chemie ◽

10.1002/ange.201915938 ◽

2019 ◽

Vol 132 (6) ◽

pp. 2146-2146

Author(s):

Tomoaki Inukai ◽

Taichi Kano ◽

Keiji Maruoka

Keyword(s):

Phase Transfer ◽

Quaternary Carbon ◽

Asymmetric Alkylation ◽

Catalytic Asymmetric

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ChemInform Abstract: Catalytic Asymmetric Synthesis of Secondary Alcohols Using Chiral cis- 1-Amino-2-hydroxy-1,2,3,4-tetrahydronaphthalene as Chiral Ligand.

ChemInform ◽

10.1002/chin.199731055 ◽

2010 ◽

Vol 28 (31) ◽

pp. no-no

Author(s):

C. M. BELLUCCI ◽

A. BERGAMINI ◽

P. G. COZZI ◽

A. PAPA ◽

E. TAGLIAVINI ◽

...

Keyword(s):

Asymmetric Synthesis ◽

Secondary Alcohols ◽

Chiral Ligand ◽

Catalytic Asymmetric Synthesis ◽

Catalytic Asymmetric

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ChemInform Abstract: Efficient Preparation of Optically Active Allylic Alcohols, 2-Furyl Alcohols and 2-Thienyl Alcohols by Catalytic Asymmetric Alkylation.

ChemInform ◽

10.1002/chin.199114100 ◽

2010 ◽

Vol 22 (14) ◽

pp. no-no

Author(s):

M. HAYASHI ◽

T. KANEKO ◽

N. OGUNI

Keyword(s):

Optically Active ◽

Allylic Alcohols ◽

Asymmetric Alkylation ◽

Catalytic Asymmetric

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Highly Enantioselective Construction of Quaternary Stereocenters on β-Keto Esters by Phase-Transfer Catalytic Asymmetric Alkylation and Michael Reaction.

ChemInform ◽

10.1002/chin.200351025 ◽

2003 ◽

Vol 34 (51) ◽

Author(s):

Takashi Ooi ◽

Takashi Miki ◽

Mika Taniguchi ◽

Misato Shirashi ◽

Mifune Takeuchi ◽

...

Keyword(s):

Michael Reaction ◽

Phase Transfer ◽

Asymmetric Alkylation ◽

Keto Esters ◽

Catalytic Asymmetric ◽

Quaternary Stereocenters

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ChemInform Abstract: Catalytic Asymmetric Synthesis of Optically Active Secondary Alcohols Deuterated on the Secondary Carbon by the Enantioselective Alkylation of Aldehydes.

ChemInform ◽

10.1002/chin.199239062 ◽

2010 ◽

Vol 23 (39) ◽

pp. no-no

Author(s):

K. SOAI ◽

Y. HIROSE ◽

S. SAKATA

Keyword(s):

Asymmetric Synthesis ◽

Optically Active ◽

Secondary Alcohols ◽

Catalytic Asymmetric Synthesis ◽

Catalytic Asymmetric ◽

Enantioselective Alkylation ◽

Secondary Carbon

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ChemInform Abstract: Catalytic Asymmetric Alkylation of Acylsilanes.

ChemInform ◽

10.1002/chin.201528242 ◽

2015 ◽

Vol 46 (28) ◽

pp. no-no

Author(s):

Jiawei Rong ◽

Rik Oost ◽

Alaric Desmarchelier ◽

Adriaan J. Minnaard ◽

Syuzanna R. Harutyunyan

Keyword(s):

Asymmetric Alkylation ◽

Catalytic Asymmetric

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