scholarly journals Preparation and characterization of sodium-ion conductive Na3BS3 glass and glass–ceramic electrolytes

2021 ◽  
Author(s):  
Fumika Tsuji ◽  
Akira Nasu ◽  
Chie Hotehama ◽  
Atsushi Sakuda ◽  
Masahiro Tatsumisago ◽  
...  
Keyword(s):  
Solid State ◽  
Glass Ceramic ◽  
Sodium Ion ◽  
Solid State Batteries ◽  
Ceramic Electrolytes ◽  
All Solid State Batteries

Glass has the highest conductivity and appropriate properties in the Na3BS3 electrolytes for all-solid-state batteries.

Interfacial Reactivity Benchmarking of the Sodium Ion Conductors Na3PS4 and Sodium β-Alumina for Protected Sodium Metal Anodes and Sodium All-Solid-State Batteries

2016 ◽  
Vol 8 (41) ◽  
pp. 28216-28224 ◽  
Author(s):  
Sebastian Wenzel ◽  
Thomas Leichtweiss ◽  
Dominik A. Weber ◽  
Joachim Sann ◽  
Wolfgang G. Zeier ◽  
...  
Keyword(s):  
Solid State ◽  
Sodium Ion ◽  
Sodium Metal ◽  
Solid State Batteries ◽  
All Solid State Batteries ◽  
Interfacial Reactivity ◽  
Metal Anodes ◽  
Ion Conductors

scholarly journals Single-step ball milling synthesis of highly Li+ conductive Li5.3PS4.3ClBr0.7 glass ceramic electrolyte enables low-impedance all-solid-state batteries

2021 ◽  
Author(s):  
Marvin Cronau ◽  
Marvin Szabo ◽  
Bernhard Roling
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Ball Milling ◽  
Glass Ceramic ◽  
Single Step ◽  
Ceramic Electrolyte ◽  
Conductive Glass ◽  
Solid State Battery ◽  
Solid State Batteries ◽  
All Solid State Batteries

Single-step ball milling synthesis of a highly conductive glass ceramic solid electrolyte enables a low-impedance all-solid-state battery.

ALL-SOLID-STATE LITHIUM SECONDARY, BATTERIES USING SULFIDE-BASED GLASS CERAMIC ELECTROLYTES

2008 ◽  
Vol 01 (01) ◽  
pp. 31-36 ◽  
Author(s):  
MASAHIRO TATSUMISAGO ◽  
AKITOSHI HAYASHI
Keyword(s):  
Solid State ◽  
Glass Ceramic ◽  
Active Material ◽  
Glass Ceramics ◽  
Cycling Performance ◽  
Lithium Secondary Batteries ◽  
Conductive Glass ◽  
Solid State Batteries ◽  
Current Densities ◽  
Ceramic Electrolytes

Highly conductive glass-ceramic electrolytes are successfully prepared in the system Li 2 S - P 2 S 5 with 70 and 80 mol% Li 2 S . The conductivities of these electrolytes are respectively 3.2 × 10-3 and 1.0 × 10-3 S cm -1 at room temperature. The precipitated crystals upon heat treatment of the glass are new superionic phase Li 7 P 3 S 11 and thio-LISICON II analog Li 3+5x P 1-x S 4, respectively. The crystal structure of the new phase Li 7 P 3 S 11 is analyzed and found to have a triclinic unit cell with space group of P-1 and to contain [Formula: see text] and [Formula: see text] ions. All-solid-state batteries using the Li 2 S - P 2 S 5 glass-ceramics are fabricated in order to evaluate the cell performance as a lithium secondary battery. The cells In /80 Li 2 S ·20 P 2 S 5 (mol%) glass-ceramic/ LiCoO 2 exhibit excellent cycling performance of over 500 times with no decrease in the discharge capacity (100 mAh g-1) at limited current densities. They also worked under very high current densities of 10 mA cm-2 when oxide- or sulfide-coated LiCoO 2 particles were used as an active material.

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