Reversible-deactivation radical polymerization of cyclic ketene acetals

2020 ◽  
Vol 11 (21) ◽  
pp. 3525-3545 ◽  
Author(s):  
Alexander W. Jackson
Keyword(s):  
Radical Polymerization ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Radical Ring ◽  
Reversible Deactivation ◽  
History Of ◽  
Cyclic Ketene Acetals ◽  
Ketene Acetals ◽  
Reversible Deactivation Radical Polymerization

This review discusses the history of reversible-deactivation radical ring-opening polymerization of cyclic ketene acetals, focusing on the preparation of degradable complex polymeric architectures.

The Radical Ring-Opening Polymerization of Cyclic Ketene Acetals Revisited: An Experimental and Theoretical Study

2020 ◽  
Author(s):  
Antoine Tardy ◽  
Noémie Gil ◽  
Christopher M. Plummer ◽  
Didier Siri ◽  
Didier Gigmes ◽  
...  
Keyword(s):  
Dft Calculations ◽  
Radical Polymerization ◽  
Kinetic Modeling ◽  
In Silico ◽  
Ring Opening ◽  
Theoretical Study ◽  
Ring Opening Polymerization ◽  
Radical Ring ◽  
Cyclic Ketene Acetals ◽  
Ketene Acetals

Radical Ring-Opening polymerization (rROP) of Cyclic Ketene Acetals (CKAs) combines the advantages of both ring-opening and radical polymerization thereby allowing the robust production of polyesters. In this article we investigate in detail the radical ring-opening polymerization of model CKA monomers and demonstrate by the combination of DFT calculations and kinetic modeling using PREDICI software that we are now able to predict <i>in silico</i> the ring-opening ability of CKA monomers<br>

The Radical Ring-Opening Polymerization of Cyclic Ketene Acetals Revisited: An Experimental and Theoretical Study

2020 ◽  
Author(s):  
Antoine Tardy ◽  
Noémie Gil ◽  
Christopher M. Plummer ◽  
Didier Siri ◽  
Didier Gigmes ◽  
...  
Keyword(s):  
Dft Calculations ◽  
Radical Polymerization ◽  
Kinetic Modeling ◽  
In Silico ◽  
Ring Opening ◽  
Theoretical Study ◽  
Ring Opening Polymerization ◽  
Radical Ring ◽  
Cyclic Ketene Acetals ◽  
Ketene Acetals

Radical Ring-Opening polymerization (rROP) of Cyclic Ketene Acetals (CKAs) combines the advantages of both ring-opening and radical polymerization thereby allowing the robust production of polyesters. In this article we investigate in detail the radical ring-opening polymerization of model CKA monomers and demonstrate by the combination of DFT calculations and kinetic modeling using PREDICI software that we are now able to predict <i>in silico</i> the ring-opening ability of CKA monomers<br>

Scope and limitations of the nitroxide-mediated radical ring-opening polymerization of cyclic ketene acetals

2013 ◽  
Vol 4 (17) ◽  
pp. 4776 ◽  
Author(s):  
Antoine Tardy ◽  
Vianney Delplace ◽  
Didier Siri ◽  
Catherine Lefay ◽  
Simon Harrisson ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Radical Ring ◽  
Cyclic Ketene Acetals ◽  
Ketene Acetals

Alternating Radical Ring-Opening Polymerization of Cyclic Ketene Acetals: Access to Tunable and Functional Polyester Copolymers

2018 ◽  
Vol 51 (14) ◽  
pp. 5079-5084 ◽  
Author(s):  
Megan R. Hill ◽  
Tomohiro Kubo ◽  
Sofia L. Goodrich ◽  
C. Adrian Figg ◽  
Brent S. Sumerlin
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Radical Ring ◽  
Cyclic Ketene Acetals ◽  
Ketene Acetals

scholarly journals Novel monomers in radical ring-opening polymerisation for biodegradable and pH responsive nanoparticles

2019 ◽  
Vol 10 (39) ◽  
pp. 5285-5288 ◽  
Author(s):  
Jenny Folini ◽  
Chao-Hung Huang ◽  
James C. Anderson ◽  
Wolfgang P. Meier ◽  
Jens Gaitzsch
Keyword(s):  
Ring Opening ◽  
Ph Sensitive ◽  
Ph Responsive ◽  
Radical Ring ◽  
Cyclic Ketene Acetals ◽  
Ketene Acetals

We report the first amine-bearing cyclic ketene acetals (CKAs) for radical ring-opening polymerisation (RROP). The resulting polyesters and their corresponding nanoparticles were biodegradable and showed the desired pH sensitive behaviour.

Ring-opening polymerization of cyclic ketene acetals and unsaturated cyclic spiro ortho esters

1991 ◽  
Vol 42-43 (1) ◽  
pp. 195-203 ◽  
Author(s):  
William J. Bailey ◽  
Jia-Ming Gu ◽  
Yin-Nian Lin ◽  
Zhi-Feng Zheng ◽  
Lin-Lin Zhou
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Cyclic Ketene Acetals ◽  
Ketene Acetals ◽  
Ortho Esters
Sign in / Sign up

Export Citation Format

Share Document