Palladium-catalyzed δ-selective reductive Heck reaction of alkenyl carbonyl compounds with aryl iodides and bromides

2020 ◽  
Vol 7 (16) ◽  
pp. 2216-2223 ◽  
Author(s):  
Yang Li ◽  
Jun-Fang Gong ◽  
Mao-Ping Song

A simple, operationally convenient and highly regioselective palladium-catalyzed reductive Heck reaction of alkenyl carbonyl compounds with aryl iodides and bromides has been developed to afford structurally diverse δ-aryl pentanoic acid derivatives.

2009 ◽  
Vol 50 (38) ◽  
pp. 5358-5360 ◽  
Author(s):  
Takashi Mino ◽  
Hiroaki Shindo ◽  
Tomoko Kaneda ◽  
Tomoko Koizumi ◽  
Yoshio Kasashima ◽  
...  

2017 ◽  
Vol 2 (31) ◽  
pp. 10143-10145 ◽  
Author(s):  
Fumitoshi Yagishita ◽  
Sota Shimokawa ◽  
Naohiro Uemura ◽  
Yasushi Yoshida ◽  
Takashi Mino ◽  
...  

2009 ◽  
Vol 15 (13) ◽  
pp. 3076-3080 ◽  
Author(s):  
Yulin Zhu ◽  
Longsheng Wang ◽  
Jian Hao ◽  
Panchao Yin ◽  
Jin Zhang ◽  
...  

ChemInform ◽  
2009 ◽  
Vol 40 (51) ◽  
pp. no-no
Author(s):  
Takashi Mino ◽  
Hiroaki Shindo ◽  
Tomoko Kaneda ◽  
Tomoko Koizumi ◽  
Yoshio Kasashima ◽  
...  

2013 ◽  
Vol 67 (7) ◽  
Author(s):  
Mojtaba Amini ◽  
Hossein Etemadi

AbstractThe Heck coupling of haloarenes with various alkenes was successfully performed in the presence of 0.5 mole % Pd(OAc)2 and 1.0 mole % d-glucosamine as an additive with K2CO3 as the optimal base in a mixture of H2O/iPrOH (φ r = 2: 1) as the reaction solvent at 80°C after 6 h. d-Glucosamine was found to be an inexpensive, air-stable, easy to available, and efficient additive in palladium-catalyzed Heck reactions of aryl iodides (67–95 % conversion) and bromides (38–72 % conversion).


2003 ◽  
Vol 5 (21) ◽  
pp. 3815-3817 ◽  
Author(s):  
Annamaria Deagostino ◽  
Cristina Prandi ◽  
Paolo Venturello

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