Synthesis, crystal structures and magnetic properties of two heterometallic {Ln8Cr4} (Ln = Gd3+ and Tb3+) complexes with one-dimensional wave chain structure
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Two heterometallic cluster {Ln8Cr4} were constructed from two classical “drum-like” {Ln4Cr2} building units associated by organic ligands HIN, displaying 1D wave chain structure. The MCE values for {Gd8Cr4} at 3 K and 7 T is 23.40 J kg−1 K−1.
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