scholarly journals A series of four novel alkaline earth metal–organic frameworks constructed of Ca(ii), Sr(ii), Ba(ii) ions and tetrahedral MTB linker: structural diversity, stability study and low/high-pressure gas adsorption properties

RSC Advances ◽  
2020 ◽  
Vol 10 (54) ◽  
pp. 32323-32334 ◽  
Author(s):  
Miroslav Almáši ◽  
Vladimír Zeleňák ◽  
Róbert Gyepes ◽  
Ľuboš Zauška ◽  
Sandrine Bourrelly
Keyword(s):  
Alkaline Earth ◽  
Gas Adsorption ◽  
Metal Organic Frameworks ◽  
Earth Metal ◽  
Structural Diversity ◽  
Stability Study ◽  
Adsorption Properties ◽  
Alkaline Earth Metal ◽  
Metal Organic ◽  
Different Gases

Four novel microporous alkaline earth metal–organic frameworks (AE-MOFs) containing methanetetrabenzoate linker (MTB): UPJS-6, UPJS-7, UPJS-8 and UPJS-9 have been successfully prepared, characterized and tested as adsorbents for different gases.

Two new alkaline earth metal organic frameworks with the diamino derivative of biphenyl-4,4′-dicarboxylate as bridging ligand: Structures, fluorescence and quenching by gas phase aldehydes

Polyhedron ◽  
2018 ◽  
Vol 153 ◽  
pp. 173-180 ◽  
Author(s):  
Stavros A. Diamantis ◽  
Anastasia D. Pournara ◽  
Antonios G. Hatzidimitriou ◽  
Manolis J. Manos ◽  
Giannis S. Papaefstathiou ◽  
...  
Keyword(s):  
Gas Phase ◽  
Alkaline Earth ◽  
Metal Organic Frameworks ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Bridging Ligand ◽  
Metal Organic

Three alkaline earth metal-organic frameworks based on fluorene-containing carboxylates: syntheses, structures and properties

2016 ◽  
Vol 60 (1) ◽  
pp. 115-121 ◽  
Author(s):  
Xinhui Zhou ◽  
Qiang Chen ◽  
Liang Li ◽  
Tao Yang ◽  
Jin Wang ◽  
...  
Keyword(s):  
Alkaline Earth ◽  
Metal Organic Frameworks ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Structures And Properties ◽  
Metal Organic

Alkaline Earth Metal–Organic Frameworks with Tailorable Ion Release: A Path for Supporting Biomineralization

2019 ◽  
Vol 11 (36) ◽  
pp. 32739-32745 ◽  
Author(s):  
Maria A. Matlinska ◽  
Michelle Ha ◽  
Bryden Hughton ◽  
Anton O. Oliynyk ◽  
Abishek K. Iyer ◽  
...  
Keyword(s):  
Alkaline Earth ◽  
Metal Organic Frameworks ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Ion Release ◽  
Metal Organic

Three Amino‐functionalized Alkaline Earth Metal‐Organic Frameworks as Catalysts for Knoevenagel Condensation

2020 ◽  
Vol 5 (37) ◽  
pp. 11510-11516 ◽  
Author(s):  
Xiuduo Song ◽  
Yanzhen He ◽  
Zhe Cai ◽  
Xiaoyun Li ◽  
Yanmin Sun ◽  
...  
Keyword(s):  
Alkaline Earth ◽  
Knoevenagel Condensation ◽  
Metal Organic Frameworks ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Metal Organic

scholarly journals Gas adsorption and structural diversity in a family of Cu(II) pyridyl-isophthalate metal–organic framework materials

2017 ◽  
Vol 375 (2084) ◽  
pp. 20160334 ◽  
Author(s):  
Jamie A. Gould ◽  
Harprit Singh Athwal ◽  
Alexander J. Blake ◽  
William Lewis ◽  
Peter Hubberstey ◽  
...  
Keyword(s):  
Dicarboxylic Acid ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Structural Diversity ◽  
Isosteric Heat ◽  
Adsorption Properties ◽  
Framework Materials ◽  
Materials By Design ◽  
Metal Organic

A family of Cu(II)-based metal–organic frameworks (MOFs) has been synthesized using three pyridyl-isophthalate ligands, H 2 L 1 (4′-(pyridin-4-yl)biphenyl-3,5-dicarboxylic acid), H 2 L 2 (4′′-(pyridin-4-yl)-1,1′:4′,1′′-terphenyl-3,5-dicarboxylic acid) and H 2 L 3 (5-[4-(pyridin-4-yl)naphthalen-1-yl]benzene-1,3-dicarboxylic acid). Although in each case the pyridyl-isophthalate ligands adopt the same pseudo-octahedral [Cu 2 (O 2 CR) 4 N 2 ] paddlewheel coordination modes, the resulting frameworks are structurally diverse, particularly in the case of the complex of Cu(II) with H 2 L 3 , which leads to three distinct supramolecular isomers, each derived from Kagomé and square nets. In contrast to [Cu(L 2 )] and the isomers of [Cu(L 3 )], [Cu(L 1 )] exhibits permanent porosity. Thus, the gas adsorption properties of [Cu(L 1 )] were investigated with N 2 , CO 2 and H 2 , and the material exhibits an isosteric heat of adsorption competitive with leading MOF sorbents for CO 2 . [Cu(L 1 )] displays high H 2 adsorption, with the density in the pores approaching that of liquid H 2 . This article is part of the themed issue ‘Coordination polymers and metal–organic frameworks: materials by design’.

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